Washing of field weathered crude oil contaminated soil with an environmentally compatible surfactant, alkyl polyglucoside | |
Han, Mei ; Ji, Guodong ; Ni, Jinren | |
刊名 | chemosphere
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2009 | |
关键词 | Ex situ soil washing Inorganic salts Simplex-centroid method Orthogonal experimental design GC/MS analysis Synergy NONIONIC SURFACTANTS ENHANCED REMEDIATION NMR-SPECTROSCOPY HEAVY OIL PHENANTHRENE SORPTION MATTER WATER SOLUBILIZATION BIOSURFACTANTS |
DOI | 10.1016/j.chemosphere.2009.05.003 |
英文摘要 | Weathered crude oil contaminated soils (COCSS), which are much more difficult to remediate than those freshly contaminated, are widespread especially at the sites of oil fields and industries. Surfactant enhanced ex situ soil washing could be used to remediate COCSs, but surfactant toxicity becomes one of the major concerns. In this study, a class of green surfactants, alkyl polyglucosides (APGs), were tested in washing the field weathered COCS with relatively high oil concentration (123 mg g(-1) dry soil) from Jilin Oilfield, Northeastern China. APG1214, characterized with longer alkyl chain, was more effective than APG0810 in crude oil removal. Adding inorganic sodium salts into APG1214 solution further improved the crude oil removal efficiency (CORE). Washing parameters (temperature, washing time. agitation speed and solution/soil ratio) were investigated and further optimized integratedly with an orthogonal design. At the optimum conditions, the CORE reached 97%. GC/MS analysis showed that the proportion of small n-alkanes (C(16)-C(23)) in residual crude oil gradually increased, which was helpful to interpret the oil removal mechanism. Moreover, eminent effect on removal of large n-alkanes was achieved from the synergy between APG1214 and inorganic salts, which was opposite to the effect when they were added separately. This study demonstrated a promising way to remediate COCS with ecologically compatible surfactant and provided guidelines for its practical application. (C) 2009 Elsevier Ltd. All rights reserved.; http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000268197400001&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=8e1609b174ce4e31116a60747a720701 ; Environmental Sciences; SCI(E); EI; PubMed; 31; ARTICLE; 5; 579-586; 76 |
语种 | 英语 |
内容类型 | 期刊论文 |
源URL | [http://ir.pku.edu.cn/handle/20.500.11897/197222] ![]() |
专题 | 环境科学与工程学院 |
推荐引用方式 GB/T 7714 | Han, Mei,Ji, Guodong,Ni, Jinren. Washing of field weathered crude oil contaminated soil with an environmentally compatible surfactant, alkyl polyglucoside[J]. chemosphere,2009. |
APA | Han, Mei,Ji, Guodong,&Ni, Jinren.(2009).Washing of field weathered crude oil contaminated soil with an environmentally compatible surfactant, alkyl polyglucoside.chemosphere. |
MLA | Han, Mei,et al."Washing of field weathered crude oil contaminated soil with an environmentally compatible surfactant, alkyl polyglucoside".chemosphere (2009). |
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