Cobalt-Catalyzed Chemoselective Transfer Hydrogenation of C=C and C=O Bonds with Alkanols | |
Jiang, Biao-Lin1,4; Ma, Shuang-Shuang2,3; Wang, Meng-Liang1; Liu, Dian-Sheng1; Xu, Bao-Hua2,3; Zhang, Suo-Jiang2,3 | |
刊名 | CHEMCATCHEM |
2019-03-20 | |
卷号 | 11期号:6页码:1701-1706 |
关键词 | bidentate ligand chemoselective reduction cobalt complex homogeneous catalysis transfer hydrogenation |
ISSN号 | 1867-3880 |
DOI | 10.1002/cctc.201900010 |
英文摘要 | An environmentally benign protocol of chemoselective transfer hydrogenation of C=C and C=O bonds with alkanols under base-free conditions is developed by this study, wherein the cobalt-bidentate phosphine catalyst precursor is commercially available and the active low-valent Co species could be generated in-situ. For the conjugation enones, the vinyl group is selectively reduced, whereas with nonconjugated alkenones, the selectivity is changed to the carbonyl group. Besides, orthoalkenyl-benzaldehydes/imines are well tolerated, and the reduction solely occurs at the C=O/C=N site with this protocol. |
资助项目 | National Basic Research Program of China (973 Program)[2015CB251401] ; National Natural Science Foundation of China (Petrochemical Joint Fund)[U1662133] |
WOS关键词 | ASYMMETRIC TRANSFER HYDROGENATION ; ENANTIOSELECTIVE TRANSFER HYDROGENATION ; BIOMIMETIC TRANSFER HYDROGENATION ; ALPHA-ALKYLATION ; N-ALKYLATION ; SELECTIVE ALKYLATION ; CARBONYL-COMPOUNDS ; AROMATIC-AMINES ; IRON COMPLEXES ; KETONES |
WOS研究方向 | Chemistry |
语种 | 英语 |
出版者 | WILEY-V C H VERLAG GMBH |
WOS记录号 | WOS:000463960000018 |
资助机构 | National Basic Research Program of China (973 Program) ; National Natural Science Foundation of China (Petrochemical Joint Fund) |
内容类型 | 期刊论文 |
源URL | [http://ir.ipe.ac.cn/handle/122111/28280] |
专题 | 中国科学院过程工程研究所 |
通讯作者 | Xu, Bao-Hua |
作者单位 | 1.Shanxi Univ, Sch Chem & Chem Engn, Taiyuan 030006, Shanxi, Peoples R China 2.Chinese Acad Sci, Beijing Key Lab Ion Liquids Clean Proc, State Key Lab Multiphase Complex Syst, Key Lab Green Proc & Engn,Inst Proc Engn, Beijing 100190, Peoples R China 3.Univ Chinese Acad Sci, Coll Chem & Chem Engn, Beijing 100049, Peoples R China 4.Inst Proc Engn, Beijing, Peoples R China |
推荐引用方式 GB/T 7714 | Jiang, Biao-Lin,Ma, Shuang-Shuang,Wang, Meng-Liang,et al. Cobalt-Catalyzed Chemoselective Transfer Hydrogenation of C=C and C=O Bonds with Alkanols[J]. CHEMCATCHEM,2019,11(6):1701-1706. |
APA | Jiang, Biao-Lin,Ma, Shuang-Shuang,Wang, Meng-Liang,Liu, Dian-Sheng,Xu, Bao-Hua,&Zhang, Suo-Jiang.(2019).Cobalt-Catalyzed Chemoselective Transfer Hydrogenation of C=C and C=O Bonds with Alkanols.CHEMCATCHEM,11(6),1701-1706. |
MLA | Jiang, Biao-Lin,et al."Cobalt-Catalyzed Chemoselective Transfer Hydrogenation of C=C and C=O Bonds with Alkanols".CHEMCATCHEM 11.6(2019):1701-1706. |
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