Construction of zn(ii)/cd(ii) coordination polymers derived from a tetrazole derivative: syntheses, structures and luminescent properties | |
Pan, Jie1,2; Jiang, Fei-Long1; Wu, Ming-Yan1; Chen, Lian1; Wan, Xiu-Yan1,2; Yang, Yan1,2; Xue, Hui1,2; Yu, Mu-Xin1,2; Hong, Mao-Chun1 | |
刊名 | Inorganic chemistry communications
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2015-06-01 | |
卷号 | 56页码:129-132 |
关键词 | Zn(ii)/cd(ii) complexes Tetrazole Crystal structure Interpenetration Luminescence |
ISSN号 | 1387-7003 |
DOI | 10.1016/j.inoche.2015.04.008 |
通讯作者 | Hong, mao-chun() |
英文摘要 | Three new coordination polymers [zn(htip)cl(h2o)](n) (1), [zn(htip)(2)](n) (2) and [cd(htip)(2)](n)center dot 2nh(2)o (3) were synthesized by reactions of zn(ii)/cd(ii) salts with a multidentate tetrazole-based ligand 2(4-(tetrazol-5-yl) phenyl)imidazo(4,5-f)(1,10)phenanthroline (h(2)tip). complex 1 possesses an infinite 1d coordination chain, and further forms the final 3d supramolecule through pi center dot center dot center dot pi stacking interactions. complexes 2 and 3 are isomorphous, and both of them feature an 8-fold interpenetrating 4-connected 3d framework with the dia topological net and the schlafli symbol of {6(6)}. in 1-3, the htip(-) ligand links two metal centers through three terminal n-donors. the structural analyses indicate that the anions and solvents can subtly influence the formation of the resulting network. moreover, the thermal stabilities and photoluminescent properties of 1-3 are investigated in the solid state. (c) 2015 elsevier b.v. all rights reserved. |
WOS关键词 | METAL-ORGANIC FRAMEWORKS ; PHOTOLUMINESCENT PROPERTIES ; LIGANDS ; COMPLEXES ; SERIES ; DIVERSITY ; CRYSTAL ; THERMOCHROMISM ; ASSEMBLIES ; NETWORKS |
WOS研究方向 | Chemistry |
WOS类目 | Chemistry, Inorganic & Nuclear |
语种 | 英语 |
出版者 | ELSEVIER SCIENCE BV |
WOS记录号 | WOS:000355045400029 |
内容类型 | 期刊论文 |
URI标识 | http://www.corc.org.cn/handle/1471x/2376552 |
专题 | 中国科学院大学 |
通讯作者 | Hong, Mao-Chun |
作者单位 | 1.Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350002, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Pan, Jie,Jiang, Fei-Long,Wu, Ming-Yan,et al. Construction of zn(ii)/cd(ii) coordination polymers derived from a tetrazole derivative: syntheses, structures and luminescent properties[J]. Inorganic chemistry communications,2015,56:129-132. |
APA | Pan, Jie.,Jiang, Fei-Long.,Wu, Ming-Yan.,Chen, Lian.,Wan, Xiu-Yan.,...&Hong, Mao-Chun.(2015).Construction of zn(ii)/cd(ii) coordination polymers derived from a tetrazole derivative: syntheses, structures and luminescent properties.Inorganic chemistry communications,56,129-132. |
MLA | Pan, Jie,et al."Construction of zn(ii)/cd(ii) coordination polymers derived from a tetrazole derivative: syntheses, structures and luminescent properties".Inorganic chemistry communications 56(2015):129-132. |
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