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Construction of zn(ii)/cd(ii) coordination polymers derived from a tetrazole derivative: syntheses, structures and luminescent properties
Pan, Jie1,2; Jiang, Fei-Long1; Wu, Ming-Yan1; Chen, Lian1; Wan, Xiu-Yan1,2; Yang, Yan1,2; Xue, Hui1,2; Yu, Mu-Xin1,2; Hong, Mao-Chun1
刊名Inorganic chemistry communications
2015-06-01
卷号56页码:129-132
关键词Zn(ii)/cd(ii) complexes Tetrazole Crystal structure Interpenetration Luminescence
ISSN号1387-7003
DOI10.1016/j.inoche.2015.04.008
通讯作者Hong, mao-chun()
英文摘要Three new coordination polymers [zn(htip)cl(h2o)](n) (1), [zn(htip)(2)](n) (2) and [cd(htip)(2)](n)center dot 2nh(2)o (3) were synthesized by reactions of zn(ii)/cd(ii) salts with a multidentate tetrazole-based ligand 2(4-(tetrazol-5-yl) phenyl)imidazo(4,5-f)(1,10)phenanthroline (h(2)tip). complex 1 possesses an infinite 1d coordination chain, and further forms the final 3d supramolecule through pi center dot center dot center dot pi stacking interactions. complexes 2 and 3 are isomorphous, and both of them feature an 8-fold interpenetrating 4-connected 3d framework with the dia topological net and the schlafli symbol of {6(6)}. in 1-3, the htip(-) ligand links two metal centers through three terminal n-donors. the structural analyses indicate that the anions and solvents can subtly influence the formation of the resulting network. moreover, the thermal stabilities and photoluminescent properties of 1-3 are investigated in the solid state. (c) 2015 elsevier b.v. all rights reserved.
WOS关键词METAL-ORGANIC FRAMEWORKS ; PHOTOLUMINESCENT PROPERTIES ; LIGANDS ; COMPLEXES ; SERIES ; DIVERSITY ; CRYSTAL ; THERMOCHROMISM ; ASSEMBLIES ; NETWORKS
WOS研究方向Chemistry
WOS类目Chemistry, Inorganic & Nuclear
语种英语
出版者ELSEVIER SCIENCE BV
WOS记录号WOS:000355045400029
内容类型期刊论文
URI标识http://www.corc.org.cn/handle/1471x/2376552
专题中国科学院大学
通讯作者Hong, Mao-Chun
作者单位1.Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350002, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714
Pan, Jie,Jiang, Fei-Long,Wu, Ming-Yan,et al. Construction of zn(ii)/cd(ii) coordination polymers derived from a tetrazole derivative: syntheses, structures and luminescent properties[J]. Inorganic chemistry communications,2015,56:129-132.
APA Pan, Jie.,Jiang, Fei-Long.,Wu, Ming-Yan.,Chen, Lian.,Wan, Xiu-Yan.,...&Hong, Mao-Chun.(2015).Construction of zn(ii)/cd(ii) coordination polymers derived from a tetrazole derivative: syntheses, structures and luminescent properties.Inorganic chemistry communications,56,129-132.
MLA Pan, Jie,et al."Construction of zn(ii)/cd(ii) coordination polymers derived from a tetrazole derivative: syntheses, structures and luminescent properties".Inorganic chemistry communications 56(2015):129-132.
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