Metastable MoS2: Crystal Structure, Electronic Band Structure, Synthetic Approach and Intriguing Physical Properties

doi:10.1002/chem.201801018

	Metastable MoS2: Crystal Structure, Electronic Band Structure, Synthetic Approach and Intriguing Physical Properties
	Zhao, Wei 1; Pan, Jie 1; Fang, Yuqiang 1; Che, Xiangli 1; Wang, Dong 1; Bu, Kejun 1; Huang, Fuqiang 1,2
刊名	Chemistry - A European Journal
	2018
ISSN号	09476539
DOI	10.1002/chem.201801018
英文摘要	The 2H molybdenum disulfide (MoS2), as a stable hexagonal phase, has been one of the most studied transition metal dichalcogenides over the past decades. In the last five years, the metastable phases of MoS2 (1T, 1T′, 1T′′, and 1T′′′) have seen a revival of interests. Different from the edge-sharing [MoS6] trigonal prisms in the 2H MoS2 phase, these metastable phases are composed of the edge-sharing [MoS6] octahedra, in which the neighboring Mo−Mo distances differ. Due to the various crystal structures and different electronic configurations of the building [MoS6] motifs, these metastable polytypes are endowed with intriguing physical properties and potential applications in diverse fields. In this Review, the recent research progress on metastable MoS2 is summarized, especially with an emphasis on the diverse synthetic approaches and the newly uncovered physical properties. The phase structures and electronic band structures are also outlined. In the end, a perspective of the future investigation on metastable MoS2 is discussed. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
出版者	Wiley-VCH Verlag
内容类型	期刊论文
源URL	[http://ir.sic.ac.cn/handle/331005/25280]
专题	中国科学院上海硅酸盐研究所
作者单位	1.State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai; 200050, China; 2.State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing; 100871, China
推荐引用方式 GB/T 7714	Zhao, Wei,Pan, Jie,Fang, Yuqiang,et al. Metastable MoS2: Crystal Structure, Electronic Band Structure, Synthetic Approach and Intriguing Physical Properties[J]. Chemistry - A European Journal,2018.
APA	Zhao, Wei.,Pan, Jie.,Fang, Yuqiang.,Che, Xiangli.,Wang, Dong.,...&Huang, Fuqiang.(2018).Metastable MoS2: Crystal Structure, Electronic Band Structure, Synthetic Approach and Intriguing Physical Properties.Chemistry - A European Journal.
MLA	Zhao, Wei,et al."Metastable MoS2: Crystal Structure, Electronic Band Structure, Synthetic Approach and Intriguing Physical Properties".Chemistry - A European Journal (2018).