Studies on absorption and regeneration for CO2 capture by aqueous ammonia

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	Studies on absorption and regeneration for CO2 capture by aqueous ammonia
	Chen, Haisheng 2; Dou, Binlin 1; Song, Yongchen 1; Xu, Yujie 2; Wang, Xueju 3; Zhang, Yi 3; Du, Xu 3; Wang, Chao 1; Zhang, Xuehui 2; Tan, Chunqin 2
刊名	INTERNATIONAL JOURNAL OF GREENHOUSE GAS CONTROL
	2012
卷号	6 页码:171-178
关键词	CO2 capture Aqueous ammonia Regeneration Non-isothermal kinetics TGA
英文摘要	To examine the characteristics of absorption and regeneration for CO2 capture by aqueous ammonia, the removal efficiency of CO2, the pH value of solution and thermal decomposition of solid product were investigated using a continuous absorption system and TGA technique. The reaction product was analyzed by XRD method. It is observed that the initial removal efficiency of CO2 can reach 90% by 10wt% concentration of aqueous ammonia. Higher concentration of aqueous ammonia from 5 to 20 wt% enables higher CO2 removal efficiency. The physical solubility of CO2 in aqueous ammonia solvent decreases, however, with increasing absorption temperature from 20 to 50 degrees C CO2 removal efficiency increased slightly due to increase the reaction rate of the dissolved CO2 with the solvent. NH4HCO3 is the main product of the CO2-NH3-H2O reaction. The regeneration results showed there was one distinct phase in the thermal decomposition of reaction product and the mass loss value during this phase was more than 95%. An improved iterative Coats-Redfern method was used to evaluate non-isothermal kinetic parameters. The reaction order model (first order) predicted accurately the main phase in the thermal decomposition of the reaction product. The values of kinetic parameters such as E and A were different for four heating rates of 5, 10, 15, and 25 K min(-1), indicating the thermal decomposition of reaction product may depend on the conditions, especially the heating rate in dynamic experiments. Based on the experimental results, system design of CO2 capture by aqueous ammonia was also discussed. (C) 2011 Elsevier Ltd. All rights reserved.
WOS标题词	Science & Technology ; Technology
类目[WOS]	Energy & Fuels ; Engineering, Environmental
研究领域[WOS]	Energy & Fuels ; Engineering
关键词[WOS]	KINETIC-PARAMETERS ; CARBON-DIOXIDE ; GREENHOUSE-GAS ; TECHNOLOGY
收录类别	SCI
语种	英语
WOS记录号	WOS:000301028000016
公开日期	2015-12-22
内容类型	期刊论文
源URL	[http://ir.etp.ac.cn/handle/311046/101510]
专题	工程热物理研究所_中国科学院工程热物理所（论文库）_期刊论文（SCI）
作者单位	1.Dalian Univ Technol, Sch Energy & Power Engn, Key Lab Ocean Energy Utilizat & Energy Conservat, Minist Educ, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Inst Engn Thermophys, Beijing 100190, Peoples R China 3.Dalian Univ Technol, Fac Chem Environm & Biol Sci & Technol, Dalian 116023, Peoples R China
推荐引用方式 GB/T 7714	Chen, Haisheng,Dou, Binlin,Song, Yongchen,et al. Studies on absorption and regeneration for CO2 capture by aqueous ammonia[J]. INTERNATIONAL JOURNAL OF GREENHOUSE GAS CONTROL,2012,6:171-178.
APA	Chen, Haisheng.,Dou, Binlin.,Song, Yongchen.,Xu, Yujie.,Wang, Xueju.,...&Tan, Chunqin.(2012).Studies on absorption and regeneration for CO2 capture by aqueous ammonia.INTERNATIONAL JOURNAL OF GREENHOUSE GAS CONTROL,6,171-178.
MLA	Chen, Haisheng,et al."Studies on absorption and regeneration for CO2 capture by aqueous ammonia".INTERNATIONAL JOURNAL OF GREENHOUSE GAS CONTROL 6(2012):171-178.