"Extracting" the Key Fragment in ETS-10 Crystallization and Its Application in AM-6 Assembly

	"Extracting" the Key Fragment in ETS-10 Crystallization and Its Application in AM-6 Assembly
	Guo, Meiling 1,2; Feng, Zhaochi 1; Li, Guanna 1; Hofmann, Jan P.3; Pidko, Evgeny A.4; Magusin, Pieter C. M. M.4; Guo, Qiang 1,2; Weckhuysen, Bert M.3; Hensen, Emiel J. M.4; Fan, Fengtao 1
刊名	chemistry-a european journal
	2012-09-01
卷号	18 期号:38 页码:12078-12084
关键词	crystallization hydrothermal synthesis Raman spectroscopy reaction mechanisms zeolites
英文摘要	the mechanism of crystallization of microporous titanosilicate ets-10 was investigated by raman spectroscopy combined with 29si magic-angle spinning (mas) nmr spectroscopy, dft calculations, and sem imaging. the formation of three-membered ring species is shown to be the key step in the hydrothermal synthesis of ets-10. they are formed by means of a complex process that involves the interaction of silicate species in the reaction mixture, which promotes the dissolution of tio2 particles. these insights into the mechanism of ets-10 growth led to the successful development of a new synthesis route to the vanadosilicate am-6 that involves the use of intermediates that contain three-membered ring species as an initiator.
类目[WOS]	chemistry, multidisciplinary
研究领域[WOS]	chemistry
关键词[WOS]	microporous titanosilicate ets-10 ; autocatalytic nucleation ; vanadium substitution ; synthesis mechanism ; quantum wires ; mfi zeolite ; raman ; framework ; titanium ; units
收录类别	SCI
语种	英语
WOS记录号	WOS:000308579100031
公开日期	2015-11-17
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/142841]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China 3.Univ Utrecht, Debye Inst NanoMat Sci, NL-3584 CG Utrecht, Netherlands 4.Eindhoven Univ Technol, Schuit Inst Catalysis, NL-5600 MB Eindhoven, Netherlands
推荐引用方式 GB/T 7714	Guo, Meiling,Feng, Zhaochi,Li, Guanna,et al. "Extracting" the Key Fragment in ETS-10 Crystallization and Its Application in AM-6 Assembly[J]. chemistry-a european journal,2012,18(38):12078-12084.
APA	Guo, Meiling.,Feng, Zhaochi.,Li, Guanna.,Hofmann, Jan P..,Pidko, Evgeny A..,...&Li, Can.(2012)."Extracting" the Key Fragment in ETS-10 Crystallization and Its Application in AM-6 Assembly.chemistry-a european journal,18(38),12078-12084.
MLA	Guo, Meiling,et al.""Extracting" the Key Fragment in ETS-10 Crystallization and Its Application in AM-6 Assembly".chemistry-a european journal 18.38(2012):12078-12084.