Control of the directions of oxidative transformation of methane over nickel-based catalysts by acid-base properties

	Control of the directions of oxidative transformation of methane over nickel-based catalysts by acid-base properties
	Miao, Q; Xiong, GX; Sheng, SS; Guo, XX
刊名	reaction kinetics and catalysis letters
	1997-11-01
卷号	62 期号:2 页码:363-370
关键词	oxidative transformation of methane nickel-based catalysts acid-base properties partial oxidation of methane oxidative coupling of methane
英文摘要	two completely different directions of the oxidative transformation of methane (otm) were performed on nickel-based catalysts due to the different acid-base properties of those catalysts. the relatively acidic laniox and linilaox/al2o3 catalysts exhibit excellent partial oxidation of methane to syngas (pom) performance. however, the relatively basic litilaox catalyst has a good oxidative coupling of methane to c-2 hydrocarbons (ocm) activity. the basic properties of the catalyst makes it difficult to reduce nickel and keeps it in the oxidized state. reduced nickel is necessary for pom and oxidized nickel for the ocm reaction.
WOS标题词	science & technology ; physical sciences
类目[WOS]	chemistry, physical
研究领域[WOS]	chemistry
关键词[WOS]	oxide ; mgo
收录类别	SCI
语种	英语
WOS记录号	WOS:000071752000025
公开日期	2015-11-17
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/142810]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
推荐引用方式 GB/T 7714	Miao, Q,Xiong, GX,Sheng, SS,et al. Control of the directions of oxidative transformation of methane over nickel-based catalysts by acid-base properties[J]. reaction kinetics and catalysis letters,1997,62(2):363-370.
APA	Miao, Q,Xiong, GX,Sheng, SS,&Guo, XX.(1997).Control of the directions of oxidative transformation of methane over nickel-based catalysts by acid-base properties.reaction kinetics and catalysis letters,62(2),363-370.
MLA	Miao, Q,et al."Control of the directions of oxidative transformation of methane over nickel-based catalysts by acid-base properties".reaction kinetics and catalysis letters 62.2(1997):363-370.