Synthesis and evaluation of molecularly imprinted core-shell carbon nanotubes for the determination of triclosan in environmental water samples | |
Gao, Ruixia1; Kong, Xuan1; Su, Fuhai2; He, Xiwen1; Chen, Langxing1; Zhang, Yukui1,3 | |
刊名 | journal of chromatography a |
2010-12-24 | |
卷号 | 1217期号:52页码:8095-8102 |
关键词 | Triclosan Molecularly imprinted polymers Carbon nanotubes Core-shell Water samples |
英文摘要 | synthetic core-shell molecularly imprinted polymers (mips) were prepared for the extraction of trace triclosan in environmental water samples. the synthesis process combined a surface molecular imprinting technique with a sol-gel process based on carbon nanotubes (cnts) coated with silica. the morphology and structure of the products were characterized by transmission electron microscopy and fourier transform infrared spectroscopy. the adsorption properties of the polymers were demonstrated by equilibrium rebinding experiments and scatchard analysis. the prepared imprinted materials exhibited fast kinetics, high capacity and favorable selectivity. the process of synthesis was quite simple and different batches of mips and non-imprinted polymers (nips) showed good reproducibility in the template binding. the feasibility of determination of triclosan from real samples was testified using spiked river and lake water samples. the recoveries of river water and lake water samples were ranged from 92.1 to 95.3% and 90.7 to 93.6%, respectively, when the environmental water samples were spiked with 0.1, 0.3, and 0.5 mu g l(-1) of tcs. in addition, the reusability of mips and nips without any deterioration in capacity was demonstrated for at least 10 repeated cycles. (c) 2010 elsevier b.v. all rights reserved. |
WOS标题词 | science & technology ; life sciences & biomedicine ; physical sciences |
类目[WOS] | biochemical research methods ; chemistry, analytical |
研究领域[WOS] | biochemistry & molecular biology ; chemistry |
关键词[WOS] | solid-phase extraction ; mass-spectrometry ; liquid-chromatography ; sorbent assays ; polymers ; nanoparticles ; contaminants ; wastewaters ; pollutants ; removal |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000285899400004 |
公开日期 | 2015-11-17 |
内容类型 | 期刊论文 |
源URL | [http://159.226.238.44/handle/321008/142002] |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China 2.Natl Inst Metrol, Beijing 100013, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116011, Peoples R China |
推荐引用方式 GB/T 7714 | Gao, Ruixia,Kong, Xuan,Su, Fuhai,et al. Synthesis and evaluation of molecularly imprinted core-shell carbon nanotubes for the determination of triclosan in environmental water samples[J]. journal of chromatography a,2010,1217(52):8095-8102. |
APA | Gao, Ruixia,Kong, Xuan,Su, Fuhai,He, Xiwen,Chen, Langxing,&Zhang, Yukui.(2010).Synthesis and evaluation of molecularly imprinted core-shell carbon nanotubes for the determination of triclosan in environmental water samples.journal of chromatography a,1217(52),8095-8102. |
MLA | Gao, Ruixia,et al."Synthesis and evaluation of molecularly imprinted core-shell carbon nanotubes for the determination of triclosan in environmental water samples".journal of chromatography a 1217.52(2010):8095-8102. |
个性服务 |
查看访问统计 |
相关权益政策 |
暂无数据 |
收藏/分享 |
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。
修改评论