A Thiourea-Oxazoline Library with Axial Chirality: Ligand Synthesis and Studies of the Palladium-Catalyzed Enantioselective Bis(methoxycarbonylation) of Terminal Olefins

	A Thiourea-Oxazoline Library with Axial Chirality: Ligand Synthesis and Studies of the Palladium-Catalyzed Enantioselective Bis(methoxycarbonylation) of Terminal Olefins
	Gao, Ying-Xiang 2,3; Chang, Le 2,3; Shi, Hang 2,3; Liang, Bo 2,3; Wongkhan, Kittiya 1; Chaiyaveij, Duangduan 1; Batsanov, Andrei S.1; Marder, Todd B.1; Li, Chuang-Chuang 2,3; Yang, Zhen 2,3
刊名	advanced synthesis & catalysis
	2010-08-01
卷号	352 期号:11-12 页码:1955-1966
关键词	asymmetric catalysis catalyst design enantioselectivity palladium thiourea-oxazoline library
英文摘要	we report herein the synthesis of novel chiral s,n-heterobidentate thiourea-oxazoline ligands and their application to palladium-catalyzed enantioselective bis(methoxycarbonylation)s of terminal olefins under mild conditions. copper salts were found to play multiple roles in this reaction. substituted 2-phenylsuccinates were obtained in >90% yield and up to 84% cc under optimized conditions.
WOS标题词	science & technology ; physical sciences
类目[WOS]	chemistry, applied ; chemistry, organic
研究领域[WOS]	chemistry
关键词[WOS]	pauson-khand reaction ; asymmetric bis(alkoxycarbonylation) reaction ; hydride transfer reduction ; cross-coupling reactions ; bis-alkoxycarbonylation ; carbon-monoxide ; silver-nitrate ; carbonylative annulation ; supported catalysts ; bioxazoline ligand
收录类别	SCI ; IC ; CCR
语种	英语
WOS记录号	WOS:000281654500024
公开日期	2015-11-17
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/142000]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Univ Durham, Dept Chem, Durham DH1 3LE, England 2.Peking Univ, Lab Chem Genom, Shenzhen Grad Sch, Shenzhen 518055, Peoples R China 3.Peking Univ, Key Lab Bioorgan Chem & Mol Engn, Minist Educ, BNLMS,Coll Chem, Beijing 100871, Peoples R China
推荐引用方式 GB/T 7714	Gao, Ying-Xiang,Chang, Le,Shi, Hang,et al. A Thiourea-Oxazoline Library with Axial Chirality: Ligand Synthesis and Studies of the Palladium-Catalyzed Enantioselective Bis(methoxycarbonylation) of Terminal Olefins[J]. advanced synthesis & catalysis,2010,352(11-12):1955-1966.
APA	Gao, Ying-Xiang.,Chang, Le.,Shi, Hang.,Liang, Bo.,Wongkhan, Kittiya.,...&Huang, Yong.(2010).A Thiourea-Oxazoline Library with Axial Chirality: Ligand Synthesis and Studies of the Palladium-Catalyzed Enantioselective Bis(methoxycarbonylation) of Terminal Olefins.advanced synthesis & catalysis,352(11-12),1955-1966.
MLA	Gao, Ying-Xiang,et al."A Thiourea-Oxazoline Library with Axial Chirality: Ligand Synthesis and Studies of the Palladium-Catalyzed Enantioselective Bis(methoxycarbonylation) of Terminal Olefins".advanced synthesis & catalysis 352.11-12(2010):1955-1966.