Advances in the synthesis of thiocarbamates

	Advances in the synthesis of thiocarbamates
	Zhang Xiaopeng 1,2; Jing Huanzhi 1; Miao Jianghuan 1; Lu Shiwei 2
刊名	progress in chemistry
	2008-08-01
卷号	20 期号:7-8 页码:1102-1107
关键词	thiocarbamates carbonylation selenium catalyst
英文摘要	thiocarbamates, a type of compounds containing many functional groups and possessing bioactivity, have been widely applied in medicine, biology and agricultural chemicals. in this paper, the main methods to synthesize thiocarbamates such as hydrolysis or-alcoholysis of thiocyanate, rearrangement reaction, phosgene derivatives method and carbonylation of nitro compounds or amines are summarized. their advantages and disadvantages are also compared. it is pointed out that selenium-catalyzed carbonylation of nitro compounds or amines with thiols to thiocarbamates is a promising method which is characterized by benign environment, high atomic economy, and "one-pot" approach.
WOS标题词	science & technology ; physical sciences
类目[WOS]	chemistry, multidisciplinary
研究领域[WOS]	chemistry
关键词[WOS]	oxidative-reductive carbonylation ; selenium-catalyzed synthesis ; human-leukocyte elastase ; carbon-monoxide ; aldehyde dehydrogenase ; elemental sulfur ; allylic thiols ; alkyl-halides ; herbicides ; amines
收录类别	SCI
语种	英语
WOS记录号	WOS:000258486600012
公开日期	2015-11-17
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/141033]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Henan Normal Univ, Coll Chem & Environm Sci, Xinxiang 453007, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Natl Engn Res Ctr Catalysis, Dalian 116011, Peoples R China
推荐引用方式 GB/T 7714	Zhang Xiaopeng,Jing Huanzhi,Miao Jianghuan,et al. Advances in the synthesis of thiocarbamates[J]. progress in chemistry,2008,20(7-8):1102-1107.
APA	Zhang Xiaopeng,Jing Huanzhi,Miao Jianghuan,&Lu Shiwei.(2008).Advances in the synthesis of thiocarbamates.progress in chemistry,20(7-8),1102-1107.
MLA	Zhang Xiaopeng,et al."Advances in the synthesis of thiocarbamates".progress in chemistry 20.7-8(2008):1102-1107.