A new application of clay-supported vanadium oxide catalyst to selective hydroxylation of benzene to phenol

	A new application of clay-supported vanadium oxide catalyst to selective hydroxylation of benzene to phenol
	Gao, Xiaohan; Xu, Jie
刊名	applied clay science
	2006-06-01
卷号	33 期号:1 页码:1-6
关键词	clay benzene phenol vanadium
英文摘要	the highly selective direct hydroxylation of benzene with hydrogen peroxide to phenol was observed on a clay-supported vanadium oxide catalyst. under mild reaction conditions at 313 k, high selectivity to phenol of 94% was realized on the clay-supported vanadium oxide catalyst at 14% conversion of benzene, comparable with the well-known ts-1 catalyst. on the other hand, vanadium on other supports and other metals on the clay support gave inferior catalytic performances. v-o-al and v-o-si bridges in the catalyst may be responsible for the reaction. (c) 2005 elsevier b.v. all rights reserved.
WOS标题词	science & technology ; physical sciences ; technology
类目[WOS]	chemistry, physical ; materials science, multidisciplinary ; mineralogy
研究领域[WOS]	chemistry ; materials science ; mineralogy
关键词[WOS]	hydrogen-peroxide ; ir-spectra ; oxidation ; complexes ; zeolites
收录类别	SCI
语种	英语
WOS记录号	WOS:000238805500001
公开日期	2015-11-17
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/140359]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
推荐引用方式 GB/T 7714	Gao, Xiaohan,Xu, Jie. A new application of clay-supported vanadium oxide catalyst to selective hydroxylation of benzene to phenol[J]. applied clay science,2006,33(1):1-6.
APA	Gao, Xiaohan,&Xu, Jie.(2006).A new application of clay-supported vanadium oxide catalyst to selective hydroxylation of benzene to phenol.applied clay science,33(1),1-6.
MLA	Gao, Xiaohan,et al."A new application of clay-supported vanadium oxide catalyst to selective hydroxylation of benzene to phenol".applied clay science 33.1(2006):1-6.