Chiral separation ability of metal-complexing imprinted polymer for L-mandelic acid

	Chiral separation ability of metal-complexing imprinted polymer for L-mandelic acid
	Liu Ying; Ding Guosheng; Xu Xiuming; Hao Weiqiang; Wei Guilin; Wang Junde
刊名	chinese journal of analytical chemistry
	2006-06-01
卷号	34 期号:6 页码:871-874
关键词	molecularly imprinted polymer metal coordination-chelation interaction chiral separation mandelic acid
英文摘要	metal-complexing imprinted polymer for l-mandelic acid was prepared using cu(ii)-[n-(4-vinylbenzyl)] iminodiacetic acid as functional monomer, trimethylolpropane trimethacrylate as crosslinker and methanol as porogenic agent. chiral separation ability of metal-complexing imprinted polymer to d,l-mandelic acid was investigated by high performance liquid chromatography. the mobile phase conditions (ph, methanol content, buffer concentration, etc.) could significantly influence the chiral separation ability of metal-complexing imprinted polymer. highly chiral selective to the template molecule by metal-complexing imprinted polymer was achieved as ph 7-9 of the mobile phase; the chiral separation ability of metal-complexing imprinted polymer was increased with the increase of methanol content and buffer concentration. it is suggested the feasibility to prepare highly selective molecularly imprinted polymer in polar solvent.
WOS标题词	science & technology ; physical sciences
类目[WOS]	chemistry, analytical
研究领域[WOS]	chemistry
关键词[WOS]	template-mediated synthesis ; recognition
收录类别	SCI
语种	英语
WOS记录号	WOS:000240869900031
公开日期	2015-11-17
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/140293]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116012, Peoples R China
推荐引用方式 GB/T 7714	Liu Ying,Ding Guosheng,Xu Xiuming,et al. Chiral separation ability of metal-complexing imprinted polymer for L-mandelic acid[J]. chinese journal of analytical chemistry,2006,34(6):871-874.
APA	Liu Ying,Ding Guosheng,Xu Xiuming,Hao Weiqiang,Wei Guilin,&Wang Junde.(2006).Chiral separation ability of metal-complexing imprinted polymer for L-mandelic acid.chinese journal of analytical chemistry,34(6),871-874.
MLA	Liu Ying,et al."Chiral separation ability of metal-complexing imprinted polymer for L-mandelic acid".chinese journal of analytical chemistry 34.6(2006):871-874.