Preparation and evaluation of dodecyl bonded zirconia stationary phase for high performance liquid chromatography
Zhang, QH; Zhang, YK; Li, T; Zhang, WB; Feng, YQ; Da, SL
刊名chinese journal of analytical chemistry
2002-02-01
卷号30期号:2页码:134-139
关键词high performance liquid chromatography stationary phase C-12-zirconia
英文摘要the c-12-alkyl phase was synthesized for zirconia substrate. the chromatographic properties of the stationary phase have been investigated by reversed-phase high-performance liquid chromatography with polycyclic aromatic hydrocarbon (pah), alkylbenzenes, anilines, pyridines and phenols as probes. the influence of organic modifier composition was studied. the new stationary phase, similar to a silica-based reversed-phase stationary phase, has hydrophobic properties. the chromatographic behavior of the basic solutes depends mainly on hydrophobic interactions between the solutes and the hydrophobic moiety of the stationary phase. lewis acidic sites on the surface of the stationary phase play an important role in the retention of phenols.
WOS标题词science & technology ; physical sciences
类目[WOS]chemistry, analytical
研究领域[WOS]chemistry
关键词[WOS]amino-acids ; porous zirconia ; peptides ; proteins ; silica
收录类别SCI
语种英语
WOS记录号WOS:000174372200002
公开日期2015-11-10
内容类型期刊论文
源URL[http://159.226.238.44/handle/321008/139125]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116011, Peoples R China
2.Wuhan Univ, Dept Chem, Wuhan 430072, Peoples R China
推荐引用方式
GB/T 7714
Zhang, QH,Zhang, YK,Li, T,et al. Preparation and evaluation of dodecyl bonded zirconia stationary phase for high performance liquid chromatography[J]. chinese journal of analytical chemistry,2002,30(2):134-139.
APA Zhang, QH,Zhang, YK,Li, T,Zhang, WB,Feng, YQ,&Da, SL.(2002).Preparation and evaluation of dodecyl bonded zirconia stationary phase for high performance liquid chromatography.chinese journal of analytical chemistry,30(2),134-139.
MLA Zhang, QH,et al."Preparation and evaluation of dodecyl bonded zirconia stationary phase for high performance liquid chromatography".chinese journal of analytical chemistry 30.2(2002):134-139.
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