Redox Tuning of a Direct Asymmetric Aldol Reaction

	Redox Tuning of a Direct Asymmetric Aldol Reaction
	Zhang, Qiying 1; Cui, Xiuling 1; Zhang, Long 2; Luo, Sanzhong 2; Wang, Hui 1; Wu, Yangjie 1
刊名	ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
	2015-04-20
卷号	54 期号:17 页码:5210-5213
关键词	aldol reaction asymmetric catalysis iron organocatalysis redox chemistry
英文摘要	Presented herein is a redox tuning strategy for asymmetric aminocatalysis with a designed chiral ferrocenophane. Under redox control, the ferrocenophane catalyst efficiently catalyzes the asymmetric aldol reaction at room temperature with excellent yield and good stereoselectivity. Moreover, the redox-active ferrocene moiety also served as phase-tag to facilitate catalyst recovery and reuse. The catalyst can be reused for five cycles without much loss of activity. Ferrocenium of the oxidized ferrocenophane was proposed to serve as Lewis acidic site, thus accounting for the stereo control.
收录类别	SCI
语种	英语
公开日期	2015-11-02
内容类型	期刊论文
源URL	[http://ir.iccas.ac.cn/handle/121111/28030]
专题	化学研究所_分子识别与功能实验室
作者单位	1.Zhengzhou Univ, Henan Key Lab Chem Biol & Organ Chem, Key Lab Appl Chem Henan Univ, Dept Chem, Zhengzhou 450052, Peoples R China 2.Chinese Acad Sci, BNLMS, CAS Key Lab Mol Recognit & Funct, Inst Chem, Beijing 100190, Peoples R China
推荐引用方式 GB/T 7714	Zhang, Qiying,Cui, Xiuling,Zhang, Long,et al. Redox Tuning of a Direct Asymmetric Aldol Reaction[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2015,54(17):5210-5213.
APA	Zhang, Qiying,Cui, Xiuling,Zhang, Long,Luo, Sanzhong,Wang, Hui,&Wu, Yangjie.(2015).Redox Tuning of a Direct Asymmetric Aldol Reaction.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,54(17),5210-5213.
MLA	Zhang, Qiying,et al."Redox Tuning of a Direct Asymmetric Aldol Reaction".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 54.17(2015):5210-5213.