Three 3d-5f Compounds (MxThy, M=Co, Ni, Zn) Based on p-tert-Butylcalix[8]arene: Syntheses, Structures and Magnetic Property

	Three 3d-5f Compounds (MxThy, M=Co, Ni, Zn) Based on p-tert-Butylcalix[8]arene: Syntheses, Structures and Magnetic Property
	Du,Shang-Chao ; Tan,Hua-Qiao ; Bi,Yan-Feng ; Yu,Yang ; Liao,Wu-Ping
刊名	无机化学学报 chinese journal of inorganic chemistry
	2014
卷号	30 期号:4 页码:749-756
关键词	CRYSTAL-STRUCTURE COMPLEXES CALIXARENES CLUSTERS METAL TB DY LN
通讯作者	liao,wp
英文摘要	three compounds, [co2th4(hc8a)(2)o-2(oh)(2)(dmf)(6)] (1), [ni2th5(h(2)c8a) (c8a)o-4(oh)(2)(dmf)(5)(ch3oh)(2)] (2), [zn2th6(hc(8)a)(c(8)a)o-5(ch3o)(c3h6no2)(2)(dmf)(5)(ch3oh)] (3) (h(8)c8a=p-tert-butylcalix[8]arene, dmf=n,n-dimethylformide), were obtained by solvothermal method and characterized by single crystal x-ray diffraction, element analysis, and so on. all these three structures are featured by some sandwich-like units which are constructed by two tail-to-tail calix[8]arene molecules and one in-between 3d-5f polynuclear core. all the calix[8]arene molecules adopt a double-cone conformation, each cone of calix[8]arene molecule bonds one thorium cation by its lower rim, and two cones of one calixarene molecule is connected by some thorium or transition metal atoms. magnetic measurement indicates that compound 1 exhibits weak ferromagnetic interaction between the metals at low temperature. ccdc: 968469, 1; 968470, 2; 968471, 3.
收录类别	SCI
语种	英语
WOS记录号	WOS:000335628600005
内容类型	期刊论文
源URL	[http://ir.ciac.jl.cn/handle/322003/57564]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	Du,Shang-Chao,Tan,Hua-Qiao,Bi,Yan-Feng,et al. Three 3d-5f Compounds (MxThy, M=Co, Ni, Zn) Based on p-tert-Butylcalix[8]arene: Syntheses, Structures and Magnetic Property[J]. 无机化学学报 chinese journal of inorganic chemistry,2014,30(4):749-756.
APA	Du,Shang-Chao,Tan,Hua-Qiao,Bi,Yan-Feng,Yu,Yang,&Liao,Wu-Ping.(2014).Three 3d-5f Compounds (MxThy, M=Co, Ni, Zn) Based on p-tert-Butylcalix[8]arene: Syntheses, Structures and Magnetic Property.无机化学学报 chinese journal of inorganic chemistry,30(4),749-756.
MLA	Du,Shang-Chao,et al."Three 3d-5f Compounds (MxThy, M=Co, Ni, Zn) Based on p-tert-Butylcalix[8]arene: Syntheses, Structures and Magnetic Property".无机化学学报 chinese journal of inorganic chemistry 30.4(2014):749-756.