Poly(L-lactide)/Poly(D-lactide)/Clay Nanocomposites: Enhanced Dispersion, Crystallization, Mechanical Properties, and Hydrolytic Degradation | |
Li, Yi ; Han, Changyu ; Zhang, Xin ; Xu,Kun ; Bian,Junjia ; Dong,Lisong | |
刊名 | polymer engineering and science |
2014 | |
卷号 | 54期号:4页码:914-924 |
关键词 | POLY(L-LACTIC ACID) NANOCOMPOSITES STEREOCOMPLEX CRYSTALLITES POLYLACTIDE STEREOCOMPLEX SILICATE NANOCOMPOSITES CARBON NANOTUBES MOLECULAR-WEIGHT HYBRID MATERIALS COMPOSITES MELT BEHAVIOR |
通讯作者 | han,cy |
英文摘要 | poly(l-lactide) (plla)/poly(d-lactide) (pdla)/clay nanocomposites are prepared via simple melt blending method at pdla loadings from 5 to 20 wt%. formation of the stereocomplex crystals in the nanocomposites is confirmed by differential scanning calorimetry and wide-angle x-ray diffraction (waxd). the internal structure of the nanocomposites has been established by using waxd and transmission electron microscope analyses. the dispersion of clay in the plla/pdla/clay nanocomposites can be improved as a result of increased intensity of shear during melt blending. the overall crystallization rates are faster in the plla/pdla/clay nanocomposites than in plla/clay nanocomposite and increase with an increase in the pdla loading up to 10 wt%; however, the crystallization mechanism and crystal structure of these nanocomposites remain unchanged despite the presence of pdla. the storage modulus has been apparently improved in the plla/pdla/clay nanocomposites with respect to plla/clay nanocomposite. moreover, it is found that the hydrolytic degradation rates have been enhanced obviously in the plla/pdla/clay nanocomposites than in plla/clay nanocomposite. polym. eng. sci., 54:914-924, 2014. (c) 2013 society of plastics engineers |
收录类别 | SCI |
语种 | 英语 |
公开日期 | 2015-10-27 |
内容类型 | 期刊论文 |
源URL | [http://ir.ciac.jl.cn/handle/322003/57513] |
专题 | 长春应用化学研究所_长春应用化学研究所知识产出_期刊论文 |
推荐引用方式 GB/T 7714 | Li, Yi,Han, Changyu,Zhang, Xin,et al. Poly(L-lactide)/Poly(D-lactide)/Clay Nanocomposites: Enhanced Dispersion, Crystallization, Mechanical Properties, and Hydrolytic Degradation[J]. polymer engineering and science,2014,54(4):914-924. |
APA | Li, Yi,Han, Changyu,Zhang, Xin,Xu,Kun,Bian,Junjia,&Dong,Lisong.(2014).Poly(L-lactide)/Poly(D-lactide)/Clay Nanocomposites: Enhanced Dispersion, Crystallization, Mechanical Properties, and Hydrolytic Degradation.polymer engineering and science,54(4),914-924. |
MLA | Li, Yi,et al."Poly(L-lactide)/Poly(D-lactide)/Clay Nanocomposites: Enhanced Dispersion, Crystallization, Mechanical Properties, and Hydrolytic Degradation".polymer engineering and science 54.4(2014):914-924. |
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