Microstructure characterization of short-chain branching polyethylene with differential scanning calorimetry and successive selfnucleation/annealing thermal fractionation

	Microstructure characterization of short-chain branching polyethylene with differential scanning calorimetry and successive selfnucleation/annealing thermal fractionation
	Xue, Yan-hu ; Wang, Yan-hui ; Fan, Yan-di ; Yang,He-ran ; Tang,Tao ; Bo,Shu-qin ; Ji,Xiang-ling
刊名	高分子科学(英文版) chinese journal of polymer science
	2014
卷号	32 期号:6 页码:751-757
关键词	RISING ELUTION FRACTIONATION ETHYLENE/ALPHA-OLEFIN COPOLYMERS LOW-DENSITY POLYETHYLENES CRYSTALLIZATION HETEROGENEITY DISTRIBUTIONS SEGREGATION POLYMERS CRYSTAL DSC
通讯作者	ji,xl
英文摘要	a series of the copolymers of ethylene with 1-hexene (m1-m9) synthesized by metallocene catalyst et[ind](2)zrcl2/mao was studied by differential scanning calorimetry and successive self-nucleation and annealing (ssa) thermal fractionation. the distribution of methylene sequence length (msl) in the different copolymers was determined using the ssa method. the comonomer contents of samples m4 and m5 are 2.04 mol% and 2.78 mol%, respectively. both m4 and m5 have low comonomer content and their msl distribution profiles exhibit a monotonous increase trend with their msl. the longest msl of m5 is 167, and its corresponding molar percent is 43.95%, which is higher than that of m4. moreover, the melting temperature (t (m)) of m5 is also higher than that of m4. the comonomer contents of samples m7, m8, and m9 are 8.73 mol%, 14.18 mol% and 15.05 mol%, respectively. m7, m8, and m9 have high comonomer contents, and their msl distribution profiles display unimodality. m7 has a lower peak value of 33 and a narrow msl distribution, resulting in a t (m) lower than that of m8 and m9. the msl and its distribution are also key points that influence the melting behavior of copolymers. sometimes, msl and its distribution of copolymers have a greater impact on it than the total comonomer contents, which is different from traditional views.
收录类别	SCI
语种	英语
WOS记录号	WOS:000335496600009
内容类型	期刊论文
源URL	[http://ir.ciac.jl.cn/handle/322003/57466]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	Xue, Yan-hu,Wang, Yan-hui,Fan, Yan-di,et al. Microstructure characterization of short-chain branching polyethylene with differential scanning calorimetry and successive selfnucleation/annealing thermal fractionation[J]. 高分子科学(英文版) chinese journal of polymer science,2014,32(6):751-757.
APA	Xue, Yan-hu.,Wang, Yan-hui.,Fan, Yan-di.,Yang,He-ran.,Tang,Tao.,...&Ji,Xiang-ling.(2014).Microstructure characterization of short-chain branching polyethylene with differential scanning calorimetry and successive selfnucleation/annealing thermal fractionation.高分子科学(英文版) chinese journal of polymer science,32(6),751-757.
MLA	Xue, Yan-hu,et al."Microstructure characterization of short-chain branching polyethylene with differential scanning calorimetry and successive selfnucleation/annealing thermal fractionation".高分子科学(英文版) chinese journal of polymer science 32.6(2014):751-757.