Thermosensitive molecularly imprinted polymers on porous carriers: Preparation, characterization and properties as novel adsorbents for bisphenol A

CORC > 烟台海岸带研究所 > 中国科学院烟台海岸带研究所 > 中科院海岸带环境过程与生态修复重点实验室

	Thermosensitive molecularly imprinted polymers on porous carriers: Preparation, characterization and properties as novel adsorbents for bisphenol A
	Dong, Ruichen 1,2; Li, Jinhua2 ; Xiong, Hua 1; Lu, Wenhui 2; Peng, Hailong 1; Chen, Lingxin2
刊名	TALANTA
	2014-12-01
卷号	130 页码:182-191
关键词	Molecularly imprinted polymers Thermosensitive polymers Bisphenol A Surface imprinting
ISSN号	0039-9140
通讯作者	Xiong, H (reprint author), Nanchang Univ, State Key Lab Food Sci & Technol, Nanchang 330047, Peoples R China. huaxiong100@126.com ; lxchen@yic.ac.cn
产权排序	[Dong, Ruichen; Xiong, Hua; Peng, Hailong] Nanchang Univ, State Key Lab Food Sci & Technol, Nanchang 330047, Peoples R China; [Dong, Ruichen; Li, Jinhua; Lu, Wenhui; Chen, Lingxin] Chinese Acad Sci, Yantai Inst Coastal Zone Res, Key Lab Coastal Environm Proc & Ecol Remediat, Yantai 264003, Peoples R China
中文摘要	Thermosensitive molecularly imprinted polymers (T-Mips) on porous carriers were prepared via the synergy of dual functional monomers of 4-vinylpyridine (VP) and N-isopropylacrylamide (NIPAM), for selective recognition and controlled adsorption and release of bisphenol A (BPA) by the temperature regulation. The porous polymer supporter was synthesized by multistep swelling of polystyrene and then both the NIPAM with temperature responsiveness and the basic monomers of VP were grafted on them in a simple way. The resultant T-MIPs showed high binding capacity, fast kinetics, and the adsorption processes were found to follow Langmuir-Freundlich isotherm and pseudo-second-order kinetic models. The adsorption capacity increased slightly along with the rise of temperature (such as 20 degrees C) under lower critical solution temperature (LCST, 33 degrees C) and decreased fast above LCST (such as 50 degrees C). Subsequently, the T-MIPs were employed as novel adsorbents for selective solid-phase extraction (SPE) of BPA from seawater and yogurt samples. Satisfying recoveries in the range of 94.83-98.47% were obtained with the precision of 3.21% at ambient temperature (20 degrees C). Through 6 adsorption-desorption cycles, the reusable T-MIPs exhibited a good recoverability with the relative standard error within 9.8%. The smart T-MIPs provided great potentials for selective identification, adsorption/release and removal of BPA by simple stimuli responsive regulation. (C) 2014 Elsevier B.V. All rights reserved.
英文摘要	Thermosensitive molecularly imprinted polymers (T-Mips) on porous carriers were prepared via the synergy of dual functional monomers of 4-vinylpyridine (VP) and N-isopropylacrylamide (NIPAM), for selective recognition and controlled adsorption and release of bisphenol A (BPA) by the temperature regulation. The porous polymer supporter was synthesized by multistep swelling of polystyrene and then both the NIPAM with temperature responsiveness and the basic monomers of VP were grafted on them in a simple way. The resultant T-MIPs showed high binding capacity, fast kinetics, and the adsorption processes were found to follow Langmuir-Freundlich isotherm and pseudo-second-order kinetic models. The adsorption capacity increased slightly along with the rise of temperature (such as 20 degrees C) under lower critical solution temperature (LCST, 33 degrees C) and decreased fast above LCST (such as 50 degrees C). Subsequently, the T-MIPs were employed as novel adsorbents for selective solid-phase extraction (SPE) of BPA from seawater and yogurt samples. Satisfying recoveries in the range of 94.83-98.47% were obtained with the precision of 3.21% at ambient temperature (20 degrees C). Through 6 adsorption-desorption cycles, the reusable T-MIPs exhibited a good recoverability with the relative standard error within 9.8%. The smart T-MIPs provided great potentials for selective identification, adsorption/release and removal of BPA by simple stimuli responsive regulation. (C) 2014 Elsevier B.V. All rights reserved.
学科主题	Chemistry, Analytical
研究领域[WOS]	Chemistry
关键词[WOS]	SOLID-PHASE EXTRACTION ; SELECTIVE RECOGNITION ; FUNCTIONAL MONOMERS ; DUMMY TEMPLATE ; WATER SAMPLES ; CHROMATOGRAPHY ; SORBENT ; LIQUID ; SHELL
收录类别	SCI
语种	英语
WOS记录号	WOS:000341897800026
内容类型	期刊论文
源URL	[http://ir.yic.ac.cn/handle/133337/8690]
专题	烟台海岸带研究所_中科院海岸带环境过程与生态修复重点实验室
作者单位	1.Nanchang Univ, State Key Lab Food Sci & Technol, Nanchang 330047, Peoples R China 2.Chinese Acad Sci, Yantai Inst Coastal Zone Res, Key Lab Coastal Environm Proc & Ecol Remediat, Yantai 264003, Peoples R China
推荐引用方式 GB/T 7714	Dong, Ruichen,Li, Jinhua,Xiong, Hua,et al. Thermosensitive molecularly imprinted polymers on porous carriers: Preparation, characterization and properties as novel adsorbents for bisphenol A[J]. TALANTA,2014,130:182-191.
APA	Dong, Ruichen,Li, Jinhua,Xiong, Hua,Lu, Wenhui,Peng, Hailong,&Chen, Lingxin.(2014).Thermosensitive molecularly imprinted polymers on porous carriers: Preparation, characterization and properties as novel adsorbents for bisphenol A.TALANTA,130,182-191.
MLA	Dong, Ruichen,et al."Thermosensitive molecularly imprinted polymers on porous carriers: Preparation, characterization and properties as novel adsorbents for bisphenol A".TALANTA 130(2014):182-191.