Photodissociation studies of cyclopentyl bromide at 234 and 266 nm using velocity ion imaging technique
Ghazal, Ahmed Yousif; Liu, Yuzhu; Wang, Yanmei; Hu, Changjin; Zhang, Bing1
刊名CHEMICAL PHYSICS LETTERS
2011-07-26
卷号511期号:1-3页码:39-44
通讯作者张冰
产权排序第一
英文摘要The photodissociation dynamics of cyclopentyl bromide at 234 and 266 nm were investigated using velocity ion imaging. Translational energy distributions of Br and Br* have been fitted by two Gaussian functions. It is possible that they are originated from different conformational structures. Three Gaussian functions are required to fit the distributions of Br* at 266 nm, which is attributed to the multiphoton dissociative ionization. The rigid radical limits of the impulsive model have been applied to the related energy partitioning. The branching ratios and the relative quantum yields were determined; the results indicated that ground-state bromine was the major dissociation product. (C) 2011 Elsevier B.V. All rights reserved.
学科主题原子分子物理学
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Physical ; Physics, Atomic, Molecular & Chemical
研究领域[WOS]Chemistry ; Physics
关键词[WOS]AB-INITIO CALCULATIONS ; MULTIPHOTON IONIZATION ; EQUATORIAL CONFORMERS ; MICROWAVE-SPECTRUM ; BROMOCYCLOPENTANE ; DYNAMICS ; CHLOROCYCLOPENTANE ; SPECTROSCOPY ; DEPENDENCE ; MOTION
收录类别SCI
语种英语
WOS记录号WOS:000292687900008
内容类型期刊论文
源URL[http://ir.wipm.ac.cn/handle/112942/1762]  
专题武汉物理与数学研究所_2011年以前论文发表(包括2011年)
作者单位1.Chinese Acad Sci, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan Inst Phys & Math, Wuhan 430071, Peoples R China
2.Chinese Acad Sci, Grad Univ, Beijing 100039, Peoples R China
推荐引用方式
GB/T 7714
Ghazal, Ahmed Yousif,Liu, Yuzhu,Wang, Yanmei,et al. Photodissociation studies of cyclopentyl bromide at 234 and 266 nm using velocity ion imaging technique[J]. CHEMICAL PHYSICS LETTERS,2011,511(1-3):39-44.
APA Ghazal, Ahmed Yousif,Liu, Yuzhu,Wang, Yanmei,Hu, Changjin,&Zhang, Bing.(2011).Photodissociation studies of cyclopentyl bromide at 234 and 266 nm using velocity ion imaging technique.CHEMICAL PHYSICS LETTERS,511(1-3),39-44.
MLA Ghazal, Ahmed Yousif,et al."Photodissociation studies of cyclopentyl bromide at 234 and 266 nm using velocity ion imaging technique".CHEMICAL PHYSICS LETTERS 511.1-3(2011):39-44.
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