Reaction Mechanism of NH3-Selective Catalytic Reduction for NO on CrOx-CeO2 Binary Oxide
Liu Hai-Di; Li Wei-Man; Yue Ren-Liang; Chen Yun-Fa
刊名CHINESE JOURNAL OF INORGANIC CHEMISTRY
2013-11-10
卷号29期号:11页码:2399-2404
关键词Cr2O3 CeO2 SCR NOx In-situ DRIFT
英文摘要In-situ Diffuse Reflectance Infrared Fourier Transform (In-situ DRIFT) Spectroscopy was employed to investigate the reaction mechanism of NH3-Selective Catalytic Reduction (SCR) upon NO on CrOx-CeO2 binary oxide at 473 K. The surface adsorbed species on the CrOx-CeO2 binary oxide during the SCR reaction were analyzed. To elucidate the reaction process more precisely, we cut off the NH3 and NO flow, respectively, in the SCR reaction and collected the resulting in-situ DRIFT spectra. The results indicate that the SCR reaction process might follow the Eley-Rideal (E-R) mechanism.
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Chemistry, Inorganic & Nuclear
研究领域[WOS]Chemistry
关键词[WOS]AMORPHOUS CHROMIA CATALYSTS ; DIFFUSE REFLECTANCE FTIR ; LOW-TEMPERATURE SCR ; NITRIC-OXIDE ; SURFACE-STRUCTURE ; MNOX-CEO2 CATALYST ; SUPERIOR CATALYST ; NH3 ; CRYSTALLINE ; ADSORPTION
收录类别SCI
语种英语
WOS记录号WOS:000327689300021
公开日期2015-05-27
内容类型期刊论文
源URL[http://ir.ipe.ac.cn/handle/122111/13751]  
专题过程工程研究所_研究所(批量导入)
作者单位Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing 100190, Peoples R China
推荐引用方式
GB/T 7714
Liu Hai-Di,Li Wei-Man,Yue Ren-Liang,et al. Reaction Mechanism of NH3-Selective Catalytic Reduction for NO on CrOx-CeO2 Binary Oxide[J]. CHINESE JOURNAL OF INORGANIC CHEMISTRY,2013,29(11):2399-2404.
APA Liu Hai-Di,Li Wei-Man,Yue Ren-Liang,&Chen Yun-Fa.(2013).Reaction Mechanism of NH3-Selective Catalytic Reduction for NO on CrOx-CeO2 Binary Oxide.CHINESE JOURNAL OF INORGANIC CHEMISTRY,29(11),2399-2404.
MLA Liu Hai-Di,et al."Reaction Mechanism of NH3-Selective Catalytic Reduction for NO on CrOx-CeO2 Binary Oxide".CHINESE JOURNAL OF INORGANIC CHEMISTRY 29.11(2013):2399-2404.
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