Comparative investigation on the properties of carbon-supported cobalt-polypyrrole pyrolyzed at various conditions as electrocatalyst towards oxygen reduction reaction | |
Yuan, XX ; Sha, HD ; Ding, XL ; Kong, HC ; Lin, H ; Wen, W ; Huang, TZ ; Guo, Z ; Ma, ZF ; Yang, Y | |
2014 | |
会议名称 | International Conference on Electrochemical Materials and Technologies for Clean Sustainable Energy (ICES) |
会议日期 | 2013 |
会议地点 | Guangzou, PEOPLES R CHINA |
页码 | 15937—15947 |
通讯作者 | yuanxx519@163.com |
英文摘要 | A series of non-precious metal catalysts named as Co-PPy-TsOH/C towards oxygen reduction reaction (ORR) were synthesized by pyrolyzing carbon supported cobalt-polypyrrole at various temperatures for diverse durations. The catalytic activity of these catalysts was evaluated with electrochemical techniques of cyclic voltammetry, rotating disk electrode and rotating ring-disk electrode. Physicochemical techniques, such as XRD, TEM and XPS, were employed to characterize the structure/morphology of the catalysts in order to understand the effects of pyrolysis conditions on the ORR activity. The results showed that both pyrolysis temperature and the duration have essential effects on the structure/morphology as well as ORR activity of the Co-PPy-TsOH/C catalysts, pyrolyzing the precursor at 800 degrees C for 2 h is the optimal condition to synthesize the catalyst with the best ORR performance. Copyright (C) 2014, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved. |
收录类别 | SCI |
会议录 | INTERNATIONAL JOURNAL OF HYDROGEN ENERGY |
会议录出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
语种 | 英语 |
ISSN号 | 0360-3199 |
WOS记录号 | WOS:000342861500073 |
内容类型 | 会议论文 |
源URL | [http://ir.sinap.ac.cn/handle/331007/14737] |
专题 | 上海应用物理研究所_中科院上海应用物理研究所2011-2017年 |
推荐引用方式 GB/T 7714 | Yuan, XX,Sha, HD,Ding, XL,et al. Comparative investigation on the properties of carbon-supported cobalt-polypyrrole pyrolyzed at various conditions as electrocatalyst towards oxygen reduction reaction[C]. 见:International Conference on Electrochemical Materials and Technologies for Clean Sustainable Energy (ICES). Guangzou, PEOPLES R CHINA. 2013. |
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