Transesterification of mustard (Brassica nigra) seed oil with ethanol: Purification of the crude ethyl ester with activated carbon produced from de-oiled cake
Fadhil, A. B.
刊名Energy Conversion and Management
2014
卷号77期号:x页码:495-503
ISSN号0196-8904
中文摘要The present study reports the production of mustard seed oil ethyl esters (MSOEE) through alkali-catalyzed transesterification with ethanol using potassium hydroxide as a catalyst. The influence of the process parameters such as catalyst concentration, ethanol to oil molar ratio, reaction temperature, reaction duration and the catalyst type was investigated so as to find out the optimal conditions for the transesterification process. As a result, optimum conditions for production of MSOEE were found to be: 0.90% KOH wt/wt of oil, 8:1 ethanol to oil molar ratio, a reaction temperature of 60 degrees C, and a reaction time of 60 min. Dry washing method with (2.50% wt.) of the activated carbon that was produced from the de-oiled cake was used to purify the crude ethyl ester from the residual catalyst and glycerol. The transesterification process provided a yield of 94% w/w of ethyl esters with an ester content of 98.22% wt. under the optimum conditions. Properties of the produced ethyl esters satisfied the specifications prescribed by the ASTM standards. Blending MSOEE with petro diesel was also investigated. The results showed that the ethyl esters had a slight influence on the properties of petro diesel. (C) 2013 Elsevier Ltd. All rights reserved.
公开日期2015-01-28
内容类型期刊论文
源URL[http://ir.xtbg.org.cn/handle/353005/7380]  
专题西双版纳热带植物园_热带植物资源可持续利用重点实验室特色文献_小桐子相关文献
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Fadhil, A. B.. Transesterification of mustard (Brassica nigra) seed oil with ethanol: Purification of the crude ethyl ester with activated carbon produced from de-oiled cake[J]. Energy Conversion and Management,2014,77(x):495-503.
APA Fadhil, A. B..(2014).Transesterification of mustard (Brassica nigra) seed oil with ethanol: Purification of the crude ethyl ester with activated carbon produced from de-oiled cake.Energy Conversion and Management,77(x),495-503.
MLA Fadhil, A. B.."Transesterification of mustard (Brassica nigra) seed oil with ethanol: Purification of the crude ethyl ester with activated carbon produced from de-oiled cake".Energy Conversion and Management 77.x(2014):495-503.
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