Sr4B10O18(OH)(2)center dot 2H(2)O: a new UV nonlinear optical material with a [B10O23](16-) building block

CORC > 新疆理化技术研究所 > 中国科学院新疆理化技术研究所 > 中国科学院特殊环境功能材料与器件重点试验室

	Sr4B10O18(OH)(2)center dot 2H(2)O: a new UV nonlinear optical material with a [B10O23](16-) building block
	Fangyuan Zhang; Qun Jing; Fangfang Zhang; Pan, Shilie; Yang, Zhihua; Han, Jian; Zhang, Min; Han, Shujuan
刊名	Journal of Materials Chemistry C
	2014
卷号	2 期号:4 页码:667-674
ISSN号	20507534
通讯作者	Zhang, F.
英文摘要	A new ultraviolet (UV) nonlinear optical (NLO) crystal Sr4B 10O18(OH)2·2H2O has been synthesized using the hydrothermal method. It crystallizes in the triclinic space group P1 (no. 1) with lattice constants a = 6.4991(6) A˚, b = 6.5059(6) A˚, c = 11.3175(11) A˚, α = 88.458(6)°, β = 86.019(5)°, γ = 61.351(5)°, Z = 1. The fundamental building block of the structure is a [B10O23]^16- unit which consists of two stereo-isomeric configurations of [B5O 12]^9- groups. The structure exhibits a ∞[B10O18]^6- three dimensional network with 9-membered tunnels along the b-axis where the Sr cation, OH anion and H2O molecule are located. Powder second harmonic generation (SHG) measurements indicate that Sr4B10O18(OH) 2·2H2O is type-I phase-matchable and displays a SHG response of about 2 × KH2PO4. The UV-Vis-NIR diffuse reflectance spectrum shows that its cutoff edge is lower than 190 nm. Density functional theory (DFT) calculations on electronic structures and SHG coefficients confirm the experimental results.
收录类别	SCI
WOS记录号	WOS:000329069900010
公开日期	2014-11-11
内容类型	期刊论文
源URL	[http://ir.xjipc.cas.cn/handle/365002/3844]
专题	新疆理化技术研究所_中国科学院特殊环境功能材料与器件重点试验室新疆理化技术研究所_材料物理与化学研究室
作者单位	Chinese Acad Sci, Key Lab Funct Mat & Devices Special Environm, Xinjiang Key Lab Elect Informat Mat & Devices, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China；Xinjiang Univ, Coll Chem & Chem Engn, Urumqi 830046, Peoples R China；Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Fangyuan Zhang,Qun Jing,Fangfang Zhang,et al. Sr4B10O18(OH)(2)center dot 2H(2)O: a new UV nonlinear optical material with a [B10O23](16-) building block[J]. Journal of Materials Chemistry C,2014,2(4):667-674.
APA	Fangyuan Zhang.,Qun Jing.,Fangfang Zhang.,Pan, Shilie.,Yang, Zhihua.,...&Han, Shujuan.(2014).Sr4B10O18(OH)(2)center dot 2H(2)O: a new UV nonlinear optical material with a [B10O23](16-) building block.Journal of Materials Chemistry C,2(4),667-674.
MLA	Fangyuan Zhang,et al."Sr4B10O18(OH)(2)center dot 2H(2)O: a new UV nonlinear optical material with a [B10O23](16-) building block".Journal of Materials Chemistry C 2.4(2014):667-674.