Synthesis of LiCo1/3Ni1/3Mn1/3O(2) as a layered cathode material prepared by the Pechini process

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	Synthesis of LiCo1/3Ni1/3Mn1/3O(2) as a layered cathode material prepared by the Pechini process
	Li, Zhigang; Kang, Xueya; Wang, Tiandiao; Han, Ying
刊名	MATERIALS TECHNOLOGY
	2006
卷号	21 期号:4 页码:229-232
ISSN号	1066-7857
英文摘要	In a study, a layered LiCO1/ 3Mn1/3Ni1/ 3O2 include a solid-state solution method, co-precipitation, mixed hydroxide method, layered double hydroxides solid state reaction, spray dry method and the metal ecetate decomposition method. In the study, layered LiCO1/ 3Mn1/ 3Ni1/ 3O2 was first prepared by the Pechini process. Ni(NO3)2·6H2O(AR), Co(NO3)2·6H2O(AR) and Mn(NO3)2(AR) were mixed and dissolved in deionized water in a molar ration of Ni/Co/Mn =1:1:1. The aqueous solution was slowly dripped into a mixed solution of NH3·H2O and NaOH at a constant rate. The stoichiometric starting materials NiO(AR), Co(NO3)2·6H2O(AR) and Mn(CH3COO)2·H2O(AR) were dispersed in acetone and mixed. The structure and morphology of the prepared powders was characterized using Xray difraction and scanning electron microscopy. Results show that Sample 1 had a phase pure a-NaFeO2 structure and the least ion mixing degree in the lattice with fine, uniform particle sizes. They developed a well layered structure and are anticipated to display an excellent electrochemical performance. The new approach requires only low temperatures and saves on energy consumption.
收录类别	SCI ; EI
WOS记录号	WOS:000243582100006
公开日期	2014-11-11
内容类型	期刊论文
源URL	[http://ir.xjipc.cas.cn/handle/365002/4126]
专题	新疆理化技术研究所_材料物理与化学研究室
作者单位	Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China;Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Urumuqi Xinjiang 830011, Peoples R China
推荐引用方式 GB/T 7714	Li, Zhigang,Kang, Xueya,Wang, Tiandiao,et al. Synthesis of LiCo1/3Ni1/3Mn1/3O(2) as a layered cathode material prepared by the Pechini process[J]. MATERIALS TECHNOLOGY,2006,21(4):229-232.
APA	Li, Zhigang,Kang, Xueya,Wang, Tiandiao,&Han, Ying.(2006).Synthesis of LiCo1/3Ni1/3Mn1/3O(2) as a layered cathode material prepared by the Pechini process.MATERIALS TECHNOLOGY,21(4),229-232.
MLA	Li, Zhigang,et al."Synthesis of LiCo1/3Ni1/3Mn1/3O(2) as a layered cathode material prepared by the Pechini process".MATERIALS TECHNOLOGY 21.4(2006):229-232.