Recent progress in methane dehydroaromatization: From laboratory curiosities to promising technology

	Recent progress in methane dehydroaromatization: From laboratory curiosities to promising technology
	Ma, Shuqi1,2 ; Guo, Xiaoguang 1; Zhao, Lingxiao 1; Scott, Susannah 3,4; Bao, Xinhe 1
刊名	journal of energy chemistry
	2013
卷号	22 期号:1 页码:1-20
关键词	direct conversion methane methane dehydroaromatization Mo-based catalyst
通讯作者	包信和
产权排序	待补充
合作状况	英
英文摘要	direct conversion of methane to benzene or other valuable chemicals is a very promising process for the efficient application of natural gas. compared with conversion processes that require oxidants, non-oxidative direct conversion is more attractive due to high selectivity to the target product. in this paper, an alternative route for methane dehydrogenation and selective conversion to benzene and hydrogen without the participation of oxygen is discussed. a brief review of the catalysts used in methane dehydroaromatization (mda) is first given, followed by our current understanding of the location and the active phase of mo species, the reaction mechanism, the mechanism of carbonaceous deposit and the deactivation of mo/zeolite catalysts are systematically discussed. ways to improve the catalytic activity and stability are described in detail based on catalyst and reaction as well as reactor design. future prospects for methane dehydroaromatization process are also presented.
学科主题	物理化学
WOS标题词	science & technology ; physical sciences ; technology
类目[WOS]	chemistry, applied ; chemistry, physical ; energy & fuels ; engineering, chemical
研究领域[WOS]	chemistry ; energy & fuels ; engineering
关键词[WOS]	mo-based catalysts ; hydrothermal post-synthesis ; bronsted acid sites ; temperature nonoxidative activation ; galloaluminosilicate mfi zeolite ; impregnated hzsm-5 catalysts ; highly stable performance ; supersonic jet expansion ; single-pass conversion ; mo-95 nmr-spectroscopy
收录类别	SCI
资助信息	1，1
原文出处	20
语种	英语
WOS记录号	WOS:000318050700002
公开日期	2014-09-11
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/119624]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China 2.Henan Polytech Univ, Sch Phys & Chem, Jiaozuo 454000, Henan, Peoples R China 3.Univ Calif Santa Barbara, Dept Chem & Biochem, Santa Barbara, CA 93106 USA 4.Univ Calif Santa Barbara, Dept Chem Engn, Santa Barbara, CA 93106 USA
推荐引用方式 GB/T 7714	Ma, Shuqi,Guo, Xiaoguang,Zhao, Lingxiao,et al. Recent progress in methane dehydroaromatization: From laboratory curiosities to promising technology[J]. journal of energy chemistry,2013,22(1):1-20.
APA	Ma, Shuqi,Guo, Xiaoguang,Zhao, Lingxiao,Scott, Susannah,&Bao, Xinhe.(2013).Recent progress in methane dehydroaromatization: From laboratory curiosities to promising technology.journal of energy chemistry,22(1),1-20.
MLA	Ma, Shuqi,et al."Recent progress in methane dehydroaromatization: From laboratory curiosities to promising technology".journal of energy chemistry 22.1(2013):1-20.