Capture and conversion of CO2 at ambient conditions by a conjugated microporous polymer

	Capture and conversion of CO2 at ambient conditions by a conjugated microporous polymer
	Xie, Yong 1,2; Wang, Ting-Ting 1; Liu, Xiao-Huan 1; Zou, Kun 2; Deng, Wei-Qiao 1
刊名	nature communications
	2013-06-01
卷号	4 页码:1960
ISSN号	2041-1723
通讯作者	邓伟侨
产权排序	待补充
合作状况	英
英文摘要	conjugated microporous polymers are a new class of porous materials with an extended pi-conjugation in an amorphous organic framework. owing to the wide-ranging flexibility in the choice and design of components and the available control of pore parameters, these polymers can be tailored for use in various applications, such as gas storage, electronics and catalysis. here we report a class of cobalt/aluminium-coordinated conjugated microporous polymers that exhibit outstanding co2 capture and conversion performance at atmospheric pressure and room temperature. these polymers can store co2 with adsorption capacities comparable to metal-organic frameworks. the cobalt-coordinated conjugated microporous polymers can also simultaneously function as heterogeneous catalysts for the reaction of co2 and propylene oxide at atmospheric pressure and room temperature, wherein the polymers demonstrate better efficiency than a homogeneous salen-cobalt catalyst. by combining the functions of gas storage and catalysts, this strategy provides a direction for cost-effective co2 reduction processes.
学科主题	物理化学
WOS标题词	science & technology
类目[WOS]	multidisciplinary sciences
研究领域[WOS]	science & technology - other topics
关键词[WOS]	metal-organic frameworks ; carbon-dioxide ; surface-area ; cyclic carbonates ; hydrogen storage ; catalysts ; complexes ; epoxides ; copolymerization ; networks
收录类别	SCI
资助信息	1，1
原文出处	1960
语种	英语
WOS记录号	WOS:000323624100028
公开日期	2014-09-11
内容类型	期刊论文
源URL	[http://159.226.238.44/handle/321008/119092]
专题	大连化学物理研究所_中国科学院大连化学物理研究所
作者单位	1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China 2.China Three Gorges Univ, Coll Chem & Life Sci, Hubei Key Lab Nat Prod Res & Dev, Yichang 443002, Peoples R China
推荐引用方式 GB/T 7714	Xie, Yong,Wang, Ting-Ting,Liu, Xiao-Huan,et al. Capture and conversion of CO2 at ambient conditions by a conjugated microporous polymer[J]. nature communications,2013,4:1960.
APA	Xie, Yong,Wang, Ting-Ting,Liu, Xiao-Huan,Zou, Kun,&Deng, Wei-Qiao.(2013).Capture and conversion of CO2 at ambient conditions by a conjugated microporous polymer.nature communications,4,1960.
MLA	Xie, Yong,et al."Capture and conversion of CO2 at ambient conditions by a conjugated microporous polymer".nature communications 4(2013):1960.