Crystalline evolution of various CeO2 morphology via a solvothermal method
Fu, C. ; Li, R. X. ; Tang, Q. ; Li, C. Q. ; Yin, S. ; Sato, T.
2011
会议名称2nd International Solvothermal and Hydrothermal-Association Conference (ISHA 2010)
会议日期JUL 27-29, 2010
会议地点Beijing, PEOPLES R CHINA
关键词CeO2 Nanosize Morphology Solvothermal Synthesis THERMAL-CONVERSION SYSTEM MICROSTRUCTURES CEOHCO3 CE3+
期号2-5
其他题名Res. Chem. Intermed.
页码319-327
中文摘要Preparation of cerium compounds with different structures and morphology is still a challenge in powder synthesis. CeOHCO3 and CeO2 have received widespread attention because of their potential applications. In this study, a solvothermal method with one-step precipitation was used to synthesize CeO2 with different structures and morphology without use of surfactant. The effects of different experimental conditions on the morphology of CeO2 were investigated. Both X-ray diffraction and SAED patterns revealed that products changed from a single CeOHCO3 phase to a mixture of CeOHCO3 and CeO2. A single Ce(O)2 phase could always be obtained from CeOHCO3 by calcination in air at 673 K for 1 h. Moreover, the morphology of CeOHCO3 was retained. Thus CeO2 particles with different morphology, for example rod-like, prism-like, polygon-like, sphere-like, and cube-like, could be synthesized. Possible mechanisms of phase and morphology evolution are discussed.
收录类别CPCI
会议网址://WOS:000291159400022
会议录Research on Chemical Intermediates
语种英语
内容类型会议论文
源URL[http://ir.ipe.ac.cn/handle/122111/11098]  
专题过程工程研究所_研究所(批量导入)
推荐引用方式
GB/T 7714
Fu, C.,Li, R. X.,Tang, Q.,et al. Crystalline evolution of various CeO2 morphology via a solvothermal method[C]. 见:2nd International Solvothermal and Hydrothermal-Association Conference (ISHA 2010). Beijing, PEOPLES R CHINA. JUL 27-29, 2010.://WOS:000291159400022.
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