Crystalline evolution of various CeO2 morphology via a solvothermal method | |
Fu, C. ; Li, R. X. ; Tang, Q. ; Li, C. Q. ; Yin, S. ; Sato, T. | |
2011 | |
会议名称 | 2nd International Solvothermal and Hydrothermal-Association Conference (ISHA 2010) |
会议日期 | JUL 27-29, 2010 |
会议地点 | Beijing, PEOPLES R CHINA |
关键词 | CeO2 Nanosize Morphology Solvothermal Synthesis THERMAL-CONVERSION SYSTEM MICROSTRUCTURES CEOHCO3 CE3+ |
期号 | 2-5 |
其他题名 | Res. Chem. Intermed. |
页码 | 319-327 |
中文摘要 | Preparation of cerium compounds with different structures and morphology is still a challenge in powder synthesis. CeOHCO3 and CeO2 have received widespread attention because of their potential applications. In this study, a solvothermal method with one-step precipitation was used to synthesize CeO2 with different structures and morphology without use of surfactant. The effects of different experimental conditions on the morphology of CeO2 were investigated. Both X-ray diffraction and SAED patterns revealed that products changed from a single CeOHCO3 phase to a mixture of CeOHCO3 and CeO2. A single Ce(O)2 phase could always be obtained from CeOHCO3 by calcination in air at 673 K for 1 h. Moreover, the morphology of CeOHCO3 was retained. Thus CeO2 particles with different morphology, for example rod-like, prism-like, polygon-like, sphere-like, and cube-like, could be synthesized. Possible mechanisms of phase and morphology evolution are discussed. |
收录类别 | CPCI |
会议网址 | |
会议录 | Research on Chemical Intermediates |
语种 | 英语 |
内容类型 | 会议论文 |
源URL | [http://ir.ipe.ac.cn/handle/122111/11098] |
专题 | 过程工程研究所_研究所(批量导入) |
推荐引用方式 GB/T 7714 |
Fu, C.,Li, R. X.,Tang, Q.,et al. Crystalline evolution of various CeO2 morphology via a solvothermal method[C]. 见:2nd International Solvothermal and Hydrothermal-Association Conference (ISHA 2010). Beijing, PEOPLES R CHINA. JUL 27-29, 2010. |
个性服务 |
查看访问统计 |
相关权益政策 |
暂无数据 |
收藏/分享 |
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。
修改评论