Generation of solid base catalyst from waste slag for the efficient synthesis of diethyl carbonate from ethyl carbamate and ethanol

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	Generation of solid base catalyst from waste slag for the efficient synthesis of diethyl carbonate from ethyl carbamate and ethanol
	Wang, Liguo 1; Li, Huiquan 1; Xin, Shumin 1; Li, Fengjiao 1,2
刊名	CATALYSIS COMMUNICATIONS
	2014-05-05
卷号	50 期号:1 页码:49-53
关键词	Solid base Slag Diethyl carbonate Ethyl carbamate Ethanolysis
ISSN号	1566-7367
其他题名	Catal. Commun.
中文摘要	The solid base derived from abundant waste slag was prepared by co-precipitation method, and tested in the diethyl carbonate synthesis via ethanolysis of ethyl carbamate. Compared to the previous reports, much higher catalytic activity and turnover frequency (TOF) of 2926 mg(DEC)/g(cat) center dot h(-1) could be achieved. Accordingly, the correlation between the catalyst basic properties and the catalytic performance revealed that the appropriate strong basic sites facilitated the formation of DEC. Moreover, the catalyst could be readily recycled and reused for several times through facile calcination. (C) 2014 Published by Elsevier B.V.
英文摘要	The solid base derived from abundant waste slag was prepared by co-precipitation method, and tested in the diethyl carbonate synthesis via ethanolysis of ethyl carbamate. Compared to the previous reports, much higher catalytic activity and turnover frequency (TOF) of 2926 mg(DEC)/g(cat) center dot h(-1) could be achieved. Accordingly, the correlation between the catalyst basic properties and the catalytic performance revealed that the appropriate strong basic sites facilitated the formation of DEC. Moreover, the catalyst could be readily recycled and reused for several times through facile calcination. (C) 2014 Published by Elsevier B.V.
WOS标题词	Science & Technology ; Physical Sciences
类目[WOS]	Chemistry, Physical
研究领域[WOS]	Chemistry
关键词[WOS]	TRANSESTERIFICATION ; TEMPERATURE
收录类别	SCI
原文出处	://WOS:000336116700012
语种	英语
WOS记录号	WOS:000336116700012
公开日期	2014-08-28
内容类型	期刊论文
版本	出版稿
源URL	[http://ir.ipe.ac.cn/handle/122111/10979]
专题	过程工程研究所_研究所（批量导入）
作者单位	1.Chinese Acad Sci, Inst Proc & Engn, Natl Engn Lab Hydrometallurg Cleaner Prod Technol, Key Lab Green Proc & Engn, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Wang, Liguo,Li, Huiquan,Xin, Shumin,et al. Generation of solid base catalyst from waste slag for the efficient synthesis of diethyl carbonate from ethyl carbamate and ethanol[J]. CATALYSIS COMMUNICATIONS,2014,50(1):49-53.
APA	Wang, Liguo,Li, Huiquan,Xin, Shumin,&Li, Fengjiao.(2014).Generation of solid base catalyst from waste slag for the efficient synthesis of diethyl carbonate from ethyl carbamate and ethanol.CATALYSIS COMMUNICATIONS,50(1),49-53.
MLA	Wang, Liguo,et al."Generation of solid base catalyst from waste slag for the efficient synthesis of diethyl carbonate from ethyl carbamate and ethanol".CATALYSIS COMMUNICATIONS 50.1(2014):49-53.