The Cause Analysis of the Incomplete Semi-Circle Observed in High Frequency Region of EIS Obtained from TEL-Covered Pure Copper
Cheng, Qingli1,2; Chen, Zhuoyuan1
刊名INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE
2013-06-01
卷号8期号:6页码:8282-8290
关键词Incomplete capacitive semi-circle NaCl Electrochemical impedance spectroscopy Thin electrolyte layer Copper
ISSN号1452-3981
通讯作者Cheng, QL
中文摘要The occurrence of the incomplete capacitive semi-circle in the high frequency region of electrochemical impedance spectra was studied using thin electrolyte layer-covered two-electrode system. Thin electrolyte layer was made by evenly depositing NaCl particles onto the electrode surface and subsequently exposing to humid pure air with relative humidity of 84% and 25 degrees C. The incomplete capacitive semi-circle in the high frequency region was observed in low NaCl deposition density and in longer exposure duration of high NaCl deposition density. The occurrence of this incomplete capacitive semi-circle is decided by the nonuniformity of the current distribution on the electrode surface.
英文摘要The occurrence of the incomplete capacitive semi-circle in the high frequency region of electrochemical impedance spectra was studied using thin electrolyte layer-covered two-electrode system. Thin electrolyte layer was made by evenly depositing NaCl particles onto the electrode surface and subsequently exposing to humid pure air with relative humidity of 84% and 25 degrees C. The incomplete capacitive semi-circle in the high frequency region was observed in low NaCl deposition density and in longer exposure duration of high NaCl deposition density. The occurrence of this incomplete capacitive semi-circle is decided by the nonuniformity of the current distribution on the electrode surface.
学科主题Electrochemistry
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Electrochemistry
研究领域[WOS]Electrochemistry
关键词[WOS]THIN ELECTROLYTE LAYERS ; ATMOSPHERIC CORROSION ; AC-IMPEDANCE ; BEHAVIOR ; METALS ; STEEL ; IRON ; RAIN
收录类别SCI
语种英语
WOS记录号WOS:000323546100068
公开日期2014-07-17
内容类型期刊论文
源URL[http://ir.qdio.ac.cn/handle/337002/16383]  
专题海洋研究所_海洋腐蚀与防护研究发展中心
作者单位1.Chinese Acad Sci, Inst Oceanol, Natl Engn Res Ctr Marine Corros Protect, Qingdao 266071, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100039, Peoples R China
推荐引用方式
GB/T 7714
Cheng, Qingli,Chen, Zhuoyuan. The Cause Analysis of the Incomplete Semi-Circle Observed in High Frequency Region of EIS Obtained from TEL-Covered Pure Copper[J]. INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE,2013,8(6):8282-8290.
APA Cheng, Qingli,&Chen, Zhuoyuan.(2013).The Cause Analysis of the Incomplete Semi-Circle Observed in High Frequency Region of EIS Obtained from TEL-Covered Pure Copper.INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE,8(6),8282-8290.
MLA Cheng, Qingli,et al."The Cause Analysis of the Incomplete Semi-Circle Observed in High Frequency Region of EIS Obtained from TEL-Covered Pure Copper".INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE 8.6(2013):8282-8290.
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