Thermogravimetric and kinetic analysis of energy crop Jerusalem artichoke using the distributed activation energy model | |
Li, Lili1![]() ![]() ![]() | |
刊名 | JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
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2013-12-01 | |
卷号 | 114期号:3页码:1183-1189 |
关键词 | Biomass Jerusalem artichoke Pyrolysis Thermogravimetric Distributed activation energy model |
ISSN号 | 1388-6150 |
通讯作者 | Qin, S (reprint author), Chinese Acad Sci, Yantai Inst Coastal Zone Res, 17 Chunhui Rd, Yantai 264003, Peoples R China. sq0535@163.com |
产权排序 | [Li, Lili; Wang, Gang; Qin, Song] Chinese Acad Sci, Yantai Inst Coastal Zone Res, Yantai 264003, Peoples R China; [Wang, Shaoyu] China Agr Univ, Yantai 264670, Peoples R China |
中文摘要 | Jerusalem artichoke has great potential as future feedstock for bioenergy production because of its high tuber yield (up to 90 t ha(-1)), appropriate biomass characteristics, low input demand, and positive environmental impact. The pyrolytic and kinetic characteristics of Jerusalem artichoke tubers were analyzed at heating rates of 5, 10, 20 and 30 A degrees C min(-1). TG and DTG curves in an inert (nitrogen) atmosphere suggested that there were three distinct stages of mass loss and the major loss occurs between about 190-380 A degrees C. Heating rate brought a lateral shift toward right in the temperature. And, it not only affects the temperature at which the highest mass loss rate reached, but also affect the maximum rate of mass loss. The distributed activation energy model (DAEM) was used to study the pyrolysis kinetics and provided reasonable fits to the experimental data. The activation energy (E) of tubers ranged from 146.40 to 232.45 kJ mol(-1), and the frequency factor (A) changed greatly corresponding to E values at different mass conversion. |
英文摘要 | Jerusalem artichoke has great potential as future feedstock for bioenergy production because of its high tuber yield (up to 90 t ha(-1)), appropriate biomass characteristics, low input demand, and positive environmental impact. The pyrolytic and kinetic characteristics of Jerusalem artichoke tubers were analyzed at heating rates of 5, 10, 20 and 30 A degrees C min(-1). TG and DTG curves in an inert (nitrogen) atmosphere suggested that there were three distinct stages of mass loss and the major loss occurs between about 190-380 A degrees C. Heating rate brought a lateral shift toward right in the temperature. And, it not only affects the temperature at which the highest mass loss rate reached, but also affect the maximum rate of mass loss. The distributed activation energy model (DAEM) was used to study the pyrolysis kinetics and provided reasonable fits to the experimental data. The activation energy (E) of tubers ranged from 146.40 to 232.45 kJ mol(-1), and the frequency factor (A) changed greatly corresponding to E values at different mass conversion. |
学科主题 | Chemistry, Analytical ; Chemistry, Physical |
研究领域[WOS] | Chemistry |
关键词[WOS] | PYROLYSIS CHARACTERISTICS ; THERMAL-DECOMPOSITION ; AIR ATMOSPHERE ; BIOMASS ; PRODUCTS ; WHEAT ; COAL ; L. |
收录类别 | SCI |
资助信息 | Ocean Public Welfare Scientific Research Project, State Oceanic Administration of China [201205027]; National Key Technology R&D Program of China [2013BAB01B00] |
原文出处 | http://dx.doi.org/10.1007/s10973-013-3115-2 |
语种 | 英语 |
WOS记录号 | WOS:000327460300030 |
公开日期 | 2014-07-08 |
内容类型 | 期刊论文 |
源URL | [http://ir.yic.ac.cn/handle/133337/7039] ![]() |
专题 | 烟台海岸带研究所_海岸带生物学与生物资源利用所重点实验室 |
作者单位 | 1.Chinese Acad Sci, Yantai Inst Coastal Zone Res, Yantai 264003, Peoples R China 2.China Agr Univ, Yantai 264670, Peoples R China |
推荐引用方式 GB/T 7714 | Li, Lili,Wang, Gang,Wang, Shaoyu,et al. Thermogravimetric and kinetic analysis of energy crop Jerusalem artichoke using the distributed activation energy model[J]. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY,2013,114(3):1183-1189. |
APA | Li, Lili,Wang, Gang,Wang, Shaoyu,&Qin, Song.(2013).Thermogravimetric and kinetic analysis of energy crop Jerusalem artichoke using the distributed activation energy model.JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY,114(3),1183-1189. |
MLA | Li, Lili,et al."Thermogravimetric and kinetic analysis of energy crop Jerusalem artichoke using the distributed activation energy model".JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY 114.3(2013):1183-1189. |
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