Structural Assembly from Phosphate to Germanophosphate by Applying Germanate as a Binder

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	Structural Assembly from Phosphate to Germanophosphate by Applying Germanate as a Binder
	Huang, Ya-Xi ; Liu, Biao ; Wen, Lei ; Zhang, Xin ; Sun, Wei ; Lin, Jun ; Huang, Chun-Zuo ; Zhuang, Rong-Chuan ; Mi, Jin-Xiao ; Zhao, Jing-Tai
刊名	INORGANIC CHEMISTRY
	2013
卷号	52 期号:16 页码:CONCATENATE(Sheet1!I318,-Sheet1!J318)
ISSN号	0020-1669
英文摘要	Structural assembly from phosphate to germanophosphate by applying germanate as a binder has been achieved. Two isotypic porous compounds, K-3 [M-4(II)(HPO4)(2)][Ge2O(OH)(PO4)(4)]center dot xH(2)O (M-II = Fe, Cd; x = 2 for Fe and 3 for Cd, denoted as KFeGePO-1 and KCdGePO-1, respectively), contain a known transition-metal phosphate (TMPO) layer, (2)(infinity){[M-2(HPO4)(3)](2-)}, which is built from chains of trans-edge-sharing MO6 octahedra bridged by MO5 trigonal bipyramids that were further linked and decorated by phosphate tetrahedra. The layers are bound by infinite chains of GeO5(OH) octahedra, resulting in a 3D open-framework structure with 1D 12-ring channels that are occupied by K+ ions and water molecules. The curvature of the TMPO layers and shape of the 12-ring windows can be tuned by the transition metals because of their Jahn-Teller effect.
收录类别	SCI
语种	英语
WOS记录号	WOS:000323460800003
公开日期	2014-06-13
内容类型	期刊论文
源URL	[http://ir.sinap.ac.cn/handle/331007/13917]
专题	上海应用物理研究所_中科院上海应用物理研究所2011-2017年
推荐引用方式 GB/T 7714	Huang, Ya-Xi,Liu, Biao,Wen, Lei,et al. Structural Assembly from Phosphate to Germanophosphate by Applying Germanate as a Binder[J]. INORGANIC CHEMISTRY,2013,52(16):CONCATENATE(Sheet1!I318,-Sheet1!J318).
APA	Huang, Ya-Xi.,Liu, Biao.,Wen, Lei.,Zhang, Xin.,Sun, Wei.,...&Zhao, Jing-Tai.(2013).Structural Assembly from Phosphate to Germanophosphate by Applying Germanate as a Binder.INORGANIC CHEMISTRY,52(16),CONCATENATE(Sheet1!I318,-Sheet1!J318).
MLA	Huang, Ya-Xi,et al."Structural Assembly from Phosphate to Germanophosphate by Applying Germanate as a Binder".INORGANIC CHEMISTRY 52.16(2013):CONCATENATE(Sheet1!I318,-Sheet1!J318).