Improvement in power conversion efficiency and long-term lifetime of organic photovoltaic cells by using bathophenanthroline/molybdenum oxide as compound cathode buffer layer | |
Fan D.![]() | |
刊名 | Solar Energy Materials and Solar Cells
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2013 | |
期号 | 117 |
ISSN号 | ISBN/09270248 |
英文摘要 | We demonstrate response and lifetime improvements for organic photovoltaic (OPV) by using organic bathophenanthroline (Bphen) and inorganic molybdenum oxide (MoO3) as a compound cathode buffer layer (CBL). Not only power conversion efficiency (PCE) increases by 27% but also working and storage lifetimes extend at least 10 and 60 times respectively comparing with PV cell with 5 nm thick Bphen as CBL. The optimized PV structure is ITO/CuPc (20 nm)/C60 (40 nm)/Bphen (2 nm)/MoO3 (5 nm)/Al and the CBL of the reference device is 5 nm Bphen without MoO3 layer. The achievement of PV performance and lifetime improvement by introducing such a compound CBL is attributed to appropriate level alignment between C 60, Bphen and MoO3, and stable inorganic MoO3 can prevent from superior oxygen and moisture diffusion into the C60 acceptor layer. The detailed working mechanism of the compound Bphen/MoO 3 CBL in the OPV cells is also argued. 2013 Elsevier B.V. |
收录类别 | SCI ; EI |
公开日期 | 2014-05-14 |
内容类型 | 期刊论文 |
源URL | [http://ir.ciomp.ac.cn/handle/181722/40709] ![]() |
专题 | 长春光学精密机械与物理研究所_中科院长春光机所知识产出 |
推荐引用方式 GB/T 7714 | Fan D.. Improvement in power conversion efficiency and long-term lifetime of organic photovoltaic cells by using bathophenanthroline/molybdenum oxide as compound cathode buffer layer[J]. Solar Energy Materials and Solar Cells,2013(117). |
APA | Fan D..(2013).Improvement in power conversion efficiency and long-term lifetime of organic photovoltaic cells by using bathophenanthroline/molybdenum oxide as compound cathode buffer layer.Solar Energy Materials and Solar Cells(117). |
MLA | Fan D.."Improvement in power conversion efficiency and long-term lifetime of organic photovoltaic cells by using bathophenanthroline/molybdenum oxide as compound cathode buffer layer".Solar Energy Materials and Solar Cells .117(2013). |
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