Decametallic CoII-Cluster-Based Microporous Magnetic Framework with a Semirigid Multicoordinating Ligand

	Decametallic CoII-Cluster-Based Microporous Magnetic Framework with a Semirigid Multicoordinating Ligand
	Tian JM ; Li WL ; Li B ; Zhang XY ; Tang JK ; Zhang JP
刊名	chemistry-a european journal
	2013
卷号	19 期号:16 页码:5097-5103
关键词	METAL-ORGANIC FRAMEWORK SINGLE-CHAIN MAGNET CRYSTAL TRANSFORMATION SLOW RELAXATION SELECTIVE GAS ADSORPTION MOLECULES TOPOLOGY BEHAVIOR SERIES
ISSN号	0947-6539
通讯作者	zhang jp
中文摘要	we have synthesized a microporous magnetic framework that contained supertetrahedral decametallic cobalt clusters as nodes and 4-(tris(hydroxymethyl)methyl)pyridine ligands as linkers in a nacl-like network. this complex shows canted antiferromagnetism with spin-glass behavior. after the removal of the guest molecules, the spin-canting and spin-glass behaviors are maintained. the permanent porosity was evaluated by n2-adsorption measurements. this complex mainly shows a hydrophobic nature, as validated by meoh- and water-adsorption measurements, which is consistent with the grand canonical monte carlo (gcmc) theoretical simulation.
收录类别	SCI收录期刊论文
语种	英语
WOS记录号	WOS:000317399600020
公开日期	2014-04-16
内容类型	期刊论文
源URL	[http://ir.ciac.jl.cn/handle/322003/49935]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	Tian JM,Li WL,Li B,et al. Decametallic CoII-Cluster-Based Microporous Magnetic Framework with a Semirigid Multicoordinating Ligand[J]. chemistry-a european journal,2013,19(16):5097-5103.
APA	Tian JM,Li WL,Li B,Zhang XY,Tang JK,&Zhang JP.(2013).Decametallic CoII-Cluster-Based Microporous Magnetic Framework with a Semirigid Multicoordinating Ligand.chemistry-a european journal,19(16),5097-5103.
MLA	Tian JM,et al."Decametallic CoII-Cluster-Based Microporous Magnetic Framework with a Semirigid Multicoordinating Ligand".chemistry-a european journal 19.16(2013):5097-5103.