Synthesis of Well-defined Long Chain Branched Polyethylene via Anionic Polymerization Combined with Graft-onto Method

	Synthesis of Well-defined Long Chain Branched Polyethylene via Anionic Polymerization Combined with Graft-onto Method
	Liu F ; Wang L ; Zhang GC ; Zheng J ; Tang T
刊名	chemical research in chinese universities
	2013
卷号	29 期号:3 页码:589-595
关键词	H-SHAPED POLYSTYRENES GURP-PALMEN-PLOT MELT RHEOLOGY HYDROCARBON POLYMERS POLYBUTADIENES POLYDISPERSITY HYDROGENATION COPOLYMERS BUTADIENE DYNAMICS
ISSN号	1005-9040
通讯作者	tang t
中文摘要	comb-like polyethylene(pe) was prepared via anionic polymerization combined with "graft-onto" process. the polybutadiene(pb) backbone underwent hydroxylation at 1,2-vinyl groups to obtain a controlled number of hydroxyl groups along the main chain. after the translation of hydroxyl groups to tosyl groups, a nucleophilic substitution by living anionic pb chains was achieved. the comb pe was finally obtained by the hydrogenation of the obtained unsaturated comb polymer. since the living anionic polymerization was used to prepare the backbones and the branch chains, molecular weight to molecular weight distribution(m-w/m(n)1.5) can be well-controlled in the final comb polymer, including the average number and length of branches.
收录类别	SCI收录期刊论文
语种	英语
WOS记录号	WOS:000320296900035
公开日期	2014-04-15
内容类型	期刊论文
源URL	[http://ir.ciac.jl.cn/handle/322003/49822]
专题	长春应用化学研究所_长春应用化学研究所知识产出_期刊论文
推荐引用方式 GB/T 7714	Liu F,Wang L,Zhang GC,et al. Synthesis of Well-defined Long Chain Branched Polyethylene via Anionic Polymerization Combined with Graft-onto Method[J]. chemical research in chinese universities,2013,29(3):589-595.
APA	Liu F,Wang L,Zhang GC,Zheng J,&Tang T.(2013).Synthesis of Well-defined Long Chain Branched Polyethylene via Anionic Polymerization Combined with Graft-onto Method.chemical research in chinese universities,29(3),589-595.
MLA	Liu F,et al."Synthesis of Well-defined Long Chain Branched Polyethylene via Anionic Polymerization Combined with Graft-onto Method".chemical research in chinese universities 29.3(2013):589-595.