Exploring polymeric lithium tartaric acid borate for thermally resistant polymer electrolyte of lithium batteries
Wang, Xuejiang; Liu, Zhihong; Zhang, Chuanjian; Kong, Qingshan; Yao, Jianhua; Han, Pengxian; Jiang, Wen; Xu, Hongxia; Cui, Guanglei
刊名ELECTROCHIMICA ACTA
2013-03-01
卷号92期号:92页码:132-138
关键词Polymer electrolytes Lithium salts High temperature Lithium ion batteries
英文摘要A novel polymeric lithium tartaric acid borate (PLTB) was synthesized via an one-step reaction in aqueous solution. The polymer electrolyte of PLTB@PVDF-HFP (poly(vinylidene fluoride-co-hexafluoropropene)) was developed by a doctor-blading followed by a soaking process in propylene carbonate (PC). It was manifested that the PC swollen PLTB@PVDF-HFP exhibited excellent electrochemical stability and compatibility with lithium metal electrode, high ionic conductivity and high lithium ion transference number at an operating temperature of 80 degrees C. The cells using the PC swollen PLTB@PVDF-HFP as electrolyte showed stable charge/discharge profiles, preferable rate capability and satisfactory cycling performance at high temperature. These superior performances of PC swollen PLTB@PVDF-HFP could endow this class of polymer electrolyte a very promising application in lithium batteries operating at relatively high temperature. (C) 2013 Elsevier Ltd. All rights reserved.
学科主题仿生能源系统
WOS标题词Science & Technology ; Physical Sciences
类目[WOS]Electrochemistry
研究领域[WOS]Electrochemistry
关键词[WOS]POLYANIONIC SOLID ELECTROLYTES ; WEAK COULOMB TRAPS ; ION BATTERIES ; NONAQUEOUS SOLUTIONS ; SALTS ; PERFORMANCE ; ANODE ; CONDUCTIVITY ; STABILITY ; COMPLEXES
收录类别SCI
语种英语
WOS记录号WOS:000316520100017
公开日期2014-03-21
内容类型期刊论文
源URL[http://ir.qibebt.ac.cn:8080/handle/337004/1604]  
专题青岛生物能源与过程研究所_仿生能源与储能系统团队
作者单位Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China
推荐引用方式
GB/T 7714
Wang, Xuejiang,Liu, Zhihong,Zhang, Chuanjian,et al. Exploring polymeric lithium tartaric acid borate for thermally resistant polymer electrolyte of lithium batteries[J]. ELECTROCHIMICA ACTA,2013,92(92):132-138.
APA Wang, Xuejiang.,Liu, Zhihong.,Zhang, Chuanjian.,Kong, Qingshan.,Yao, Jianhua.,...&Cui, Guanglei.(2013).Exploring polymeric lithium tartaric acid borate for thermally resistant polymer electrolyte of lithium batteries.ELECTROCHIMICA ACTA,92(92),132-138.
MLA Wang, Xuejiang,et al."Exploring polymeric lithium tartaric acid borate for thermally resistant polymer electrolyte of lithium batteries".ELECTROCHIMICA ACTA 92.92(2013):132-138.
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