One-Pot Synthesis of Pd Nanoparticle Catalysts Supported on N-Doped Carbon and Application in the Domino Carbonylation

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	One-Pot Synthesis of Pd Nanoparticle Catalysts Supported on N-Doped Carbon and Application in the Domino Carbonylation
	Li ZL(李泽龙)1,2; Liu JH(刘建华)1 ; Huang ZW(黄志威)1 ; Yang Y(杨英)1; Xia CG(夏春谷)1 ; Li FW(李福伟)1 ; Xia CG(夏春谷); Li FW(李福伟)
刊名	ACS Catalysis
	2013
卷号	3 期号:5 页码:839-845
关键词	N-doped carbon N-heterocyclic carbenes supported catalysts nanoparticles carbonylation
ISSN号	2155-5435
通讯作者	夏春谷 ; 李福伟
英文摘要	In this work, we report a novel and facile procedure for a one-pot preparation of palladium nanoparticle catalysts supported on porous N-doped carbon (Pd@CN^T) by direct carbonization of palladium-N-heterocyclic carbene coordination polymer (P-Pd-NHC). This method could be conveniently extended to the synthesis of the Ni and alloy (Pd_xNi_y) nanoparticle catalysts (Ni@CN⁸⁰⁰, Pd_xNi_y@CN⁸⁰⁰). The treatment temperature played an important role on the growth and properties of the resultant M@CN^T, wherein M@CN⁸⁰⁰ carbonized at 800 ℃ showed well-monodispersed metal nanoparticles (MNPs), graphene-like layers of the N-doped carbon supports, and strong interaction between MNPs and the support. Pd@CN⁸⁰⁰ displayed high efficiency and stable recyclability toward the domino carbonylative synthesis of pyrazole derivatives. Interestingly, its catalytic performance has been even higher than that of the representative PdCl₂(PPh₃)₂ within six runs.
学科主题	物理化学与绿色催化
收录类别	SCI
资助信息	the Chinese Academy of Sciences;the National Natural Science Foundation of China (21002106;21133011)
语种	英语
WOS记录号	WOS:000318589100006
公开日期	2013-12-19
内容类型	期刊论文
源URL	[http://210.77.64.217/handle/362003/4795]
专题	兰州化学物理研究所_OSSO国家重点实验室
通讯作者	Xia CG(夏春谷); Li FW(李福伟)
作者单位	1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Gansu, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Li ZL,Liu JH,Huang ZW,et al. One-Pot Synthesis of Pd Nanoparticle Catalysts Supported on N-Doped Carbon and Application in the Domino Carbonylation[J]. ACS Catalysis,2013,3(5):839-845.
APA	Li ZL.,Liu JH.,Huang ZW.,Yang Y.,Xia CG.,...&李福伟.(2013).One-Pot Synthesis of Pd Nanoparticle Catalysts Supported on N-Doped Carbon and Application in the Domino Carbonylation.ACS Catalysis,3(5),839-845.
MLA	Li ZL,et al."One-Pot Synthesis of Pd Nanoparticle Catalysts Supported on N-Doped Carbon and Application in the Domino Carbonylation".ACS Catalysis 3.5(2013):839-845.