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The Control of the Expansion or Compression of Colloidal Crystals Lattice with Salt Solution
Zhou, Hongwei2; Ouyang, Wenze2; Zou, Shuangyang2; Xu, Shenghua1,2
刊名NANOMATERIALS
2024-02-01
卷号14期号:4页码:11
关键词colloidal crystals lattice spacing diffusiophoresis diffusioosmosis
DOI10.3390/nano14040355
通讯作者Xu, Shenghua(xush@imech.ac.cn)
英文摘要Tuning the lattice spacing or stop bands holds great significance in the design and application of materials with colloidal crystals. Typically, particle surface modifications or the application of external physical fields are needed. In this study, we demonstrated the ability to expand or compress the lattice of colloidal crystals simply by utilizing a salt solution, without the need for any special treatments to the colloidal particles. We found that by only considering the diffusiophoresis effect we cannot explain the reversion of lattice expansion to lattice compression with the increase in the salt concentration and that the diffusioosmotic flow originating from the container wall must be taken into account. Further analysis revealed that variations in the salt concentration altered the relative amplitudes between diffusiophoresis and diffusioosmosis through changing the zeta potentials of the particles and the wall, and the competition between the particle diffusiophoresis and wall diffusioosmosis lay at the center of the underlying mechanism.
资助项目National Natural Science Foundation of China
WOS关键词CRYSTALLIZATION ; MECHANISM ; ARRAYS ; FILMS ; GEL
WOS研究方向Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics
语种英语
WOS记录号WOS:001172528500001
资助机构National Natural Science Foundation of China
内容类型期刊论文
源URL[http://dspace.imech.ac.cn/handle/311007/94555]  
专题力学研究所_国家微重力实验室
通讯作者Xu, Shenghua
作者单位1.Univ Chinese Acad Sci, Sch Engn Sci, Beijing 100049, Peoples R China
2.Chinese Acad Sci, Inst Mech, Key Lab Micrograv, Beijing 100190, Peoples R China
推荐引用方式
GB/T 7714
Zhou, Hongwei,Ouyang, Wenze,Zou, Shuangyang,et al. The Control of the Expansion or Compression of Colloidal Crystals Lattice with Salt Solution[J]. NANOMATERIALS,2024,14(4):11.
APA Zhou, Hongwei,Ouyang, Wenze,Zou, Shuangyang,&Xu, Shenghua.(2024).The Control of the Expansion or Compression of Colloidal Crystals Lattice with Salt Solution.NANOMATERIALS,14(4),11.
MLA Zhou, Hongwei,et al."The Control of the Expansion or Compression of Colloidal Crystals Lattice with Salt Solution".NANOMATERIALS 14.4(2024):11.
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