Microfabrication of Li<sub>4</sub>SiO<sub>4</sub> pebbles with complex pore structure via digital light processing: Accuracy control and properties optimizing

doi:10.1016/j.ijhydene.2023.11.353

CORC > 自动化研究所 > 中国科学院自动化研究所 > 多模态人工智能系统全国重点实验室

	Microfabrication of Li₄SiO₄ pebbles with complex pore structure via digital light processing: Accuracy control and properties optimizing
	Cai, Liang 1; Tao, Sirong 1; Shen, Zhen 2; Wan, Li 3; Liu, Ziao 1; He, Xilin 1; Zhang, Yingchun 1
刊名	INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
	2024-02-07
卷号	54 页码:1410-1421
关键词	Additive manufacturing Digital light processing Tritium breeder material Ceramic pebble Lithium orthosilicate
ISSN号	0360-3199
DOI	10.1016/j.ijhydene.2023.11.353
通讯作者	Zhang, Yingchun(zycustb@163.com)
英文摘要	Li4SiO4 ceramic pebble is deemed as the most attractive tritium breeder for fusion reactor blanket. In this work, we fabricated a novel Li4SiO4 pebble with micrometer-scale pore structure by digital light processing to verify the feasibility of complex pore structure manufacturing for future breeders. The effects of processing parameters on printing accuracy, microstructure and mechanical properties of Li4SiO4 pebbles were investigated. For synthesizing the pure Li4SiO4 phase, the optimal stoichiometric ratio of Li2SiO3 to Li2CO3 was 1:1.09 in the premixed powder. The photosensitivity of dual-phase ceramic suspension was investigated according to an attenuation model, and the overgrowth was reduced to similar to 50 mu m by using the dimension formula. After optimizing the post-processing, the radial pore structure Li4SiO4 pebbles with excellent crush load (50.3 N, standard deviation = 4.4 N) and suitable open porosity (18.3 %) can be yielded. This work provides a fresh solution to control the pore structure of tritium breeding pebbles in an unprecedented micrometer scale.
资助项目	National Natural Science Foundation of China[51972018] ; Foshan Science and Technology Innovation Team Project[2018IT100142]
WOS关键词	CERAMIC PEBBLES ; TRITIUM RELEASE ; CONCEPTUAL DESIGN ; BREEDER ; FABRICATION ; HYDROGEN ; MICROSTEREOLITHOGRAPHY ; PHOTOPOLYMERIZATION ; SUSPENSIONS ; BEHAVIOR
WOS研究方向	Chemistry ; Electrochemistry ; Energy & Fuels
语种	英语
出版者	PERGAMON-ELSEVIER SCIENCE LTD
WOS记录号	WOS:001143162800001
资助机构	National Natural Science Foundation of China ; Foshan Science and Technology Innovation Team Project
内容类型	期刊论文
源URL	[http://ir.ia.ac.cn/handle/173211/54771]
专题	多模态人工智能系统全国重点实验室
通讯作者	Zhang, Yingchun
作者单位	1.Univ Sci & Technol Beijing, Sch Mat Sci & Engn, 30 Xueyuan Rd, Beijing 100083, Peoples R China 2.Chinese Acad Sci, Inst Automat, Beijing Engn Res Ctr Intelligent Syst & Technol, State Key Lab Management & Control Complex Syst, 95 Zhongguancun E Rd, Beijing 100190, Peoples R China 3.Ten Dimens Guangdong Technol Co Ltd, 33 Informat Rd, Foshan 528225, Peoples R China
推荐引用方式 GB/T 7714	Cai, Liang,Tao, Sirong,Shen, Zhen,et al. Microfabrication of Li₄SiO₄ pebbles with complex pore structure via digital light processing: Accuracy control and properties optimizing[J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,2024,54:1410-1421.
APA	Cai, Liang.,Tao, Sirong.,Shen, Zhen.,Wan, Li.,Liu, Ziao.,...&Zhang, Yingchun.(2024).Microfabrication of Li₄SiO₄ pebbles with complex pore structure via digital light processing: Accuracy control and properties optimizing.INTERNATIONAL JOURNAL OF HYDROGEN ENERGY,54,1410-1421.
MLA	Cai, Liang,et al."Microfabrication of Li₄SiO₄ pebbles with complex pore structure via digital light processing: Accuracy control and properties optimizing".INTERNATIONAL JOURNAL OF HYDROGEN ENERGY 54(2024):1410-1421.