Effect of copper loading on synergism in CuO/CeO<sub>2</sub> nanorod catalysts for toluene combustion

doi:10.1039/d3nj04820a

CORC > 力学研究所 > 中国科学院力学研究所 > 高温气体动力学国家重点实验室

	Effect of copper loading on synergism in CuO/CeO₂ nanorod catalysts for toluene combustion
	Gao X(高鑫); Yun, Jianyu; Deng, Linlin; Yi XK(衣晓坤); Teng, Zihao; Wang, Yifan; Dou, Baojuan; Bin F(宾峰)
刊名	NEW JOURNAL OF CHEMISTRY
	2024-02-19
卷号	48 期号:8 页码:3431-3437
ISSN号	1144-0546
DOI	10.1039/d3nj04820a
通讯作者	Dou, Baojuan(bjdou@tust.edu.cn) ; Bin, Feng(binfeng@imech.ac.cn)
英文摘要	CuO/CeO2 catalysts were widely studied as an alternative to precious metal catalysts, and the Cu-Ce synergy was essential to improve the catalytic performance. In this paper, the effects of CuO loading on Cu-Ce synergy in CuO/CeO2 nanorod catalysts and their performance in toluene combustion were systematically investigated. It was found that non-equilibrium plasma facilitated the dispersion of CuO active species on the CeO2 surface. With the increase of the CuO loading from 1 wt% to 4 wt%, the Cu-Ce synergistic effect was gradually improved, which generated Cu+/Cu2+ and Ce3+/Ce4+ redox electron pairs. The highest oxygen vacancy concentration and Cu+ content of CuCe-4 (4 wt%) resulting from strong Cu-Ce synergy accelerated the activation of chemisorbed oxygen and consequently improved the efficiency of toluene catalytic combustion.
分类号	二类
资助项目	Guangxi Key Research and Development Program[AB21220040] ; Guangxi Key Research and Development Program
WOS关键词	CO OXIDATION ; CE ; PLASMA
WOS研究方向	Chemistry
语种	英语
WOS记录号	WOS:001153941500001
资助机构	Guangxi Key Research and Development Program ; Guangxi Key Research and Development Program
其他责任者	Dou, Baojuan ; Bin, Feng
内容类型	期刊论文
源URL	[http://dspace.imech.ac.cn/handle/311007/94393]
专题	力学研究所_高温气体动力学国家重点实验室
推荐引用方式 GB/T 7714	Gao X,Yun, Jianyu,Deng, Linlin,et al. Effect of copper loading on synergism in CuO/CeO₂ nanorod catalysts for toluene combustion[J]. NEW JOURNAL OF CHEMISTRY,2024,48(8):3431-3437.
APA	高鑫.,Yun, Jianyu.,Deng, Linlin.,衣晓坤.,Teng, Zihao.,...&宾峰.(2024).Effect of copper loading on synergism in CuO/CeO₂ nanorod catalysts for toluene combustion.NEW JOURNAL OF CHEMISTRY,48(8),3431-3437.
MLA	高鑫,et al."Effect of copper loading on synergism in CuO/CeO₂ nanorod catalysts for toluene combustion".NEW JOURNAL OF CHEMISTRY 48.8(2024):3431-3437.