Plasma-catalytic oxidation of toluene over MCeZrOx/TiO2 (M = Cu, Mn, Ni and Co) catalysts using a dielectric barrier discharge reactor

doi:10.1039/d3nj05057b

CORC > 力学研究所 > 中国科学院力学研究所 > 高温气体动力学国家重点实验室

	Plasma-catalytic oxidation of toluene over MCeZrO_x/TiO₂ (M = Cu, Mn, Ni and Co) catalysts using a dielectric barrier discharge reactor
	Hu, Guangtao; Ma, Yichen; Hao, Qinglan; Liu, Deliang; Dou, Baojuan; Bin F(宾峰)
刊名	NEW JOURNAL OF CHEMISTRY
	2024-02-05
卷号	48 期号:6 页码:2624-2638
ISSN号	1144-0546
DOI	10.1039/d3nj05057b
通讯作者	Ma, Yichen(yichenma@liverpool.ac.uk) ; Bin, Feng(binfeng@imech.ac.cn)
英文摘要	Plasma catalysis is recognized as a promising technology for the elimination of diluted volatile organic compounds (VOCs). In this study, a hybrid process was carried out using dielectric barrier discharge (DBD) and MCeZr/TiO2 (M = Cu, Mn, Ni, and Co) catalysts for the degradation of VOCs. The plasma-catalytic system demonstrated a substantial improvement in toluene conversion and CO2 selectivity compared to the plasma-only system owing to the synergistic effects of plasma and thermal catalysis on toluene degradation. The performance of toluene removal follows the sequence of CuCeZr/T > NiCeZr/T > CoCeZr/T > MnCeZr/T in plasma catalysis. The CuCeZr/T catalyst demonstrated the highest toluene conversion of 99.0% and a CO2 selectivity of 91.0% at a discharge power of 30 W. Energetic electrons and reactive species generated by plasma actively participate in toluene activation in the gas phase and facilitate adsorption on the catalyst surface. The redox properties between Ce4+/Ce3+ and Cu+/Cu2+ species dictated the reducibility of the CuCeZr/T catalyst, promoting oxygen cycling during toluene oxidation and leading to enhanced catalytic performance. The pathways of toluene destruction in the plasma-catalysis system are discussed based on the analysis results of GC-MS, optical emission spectroscopy and calculations of the electron-impact reactions.
分类号	二类
资助项目	National Natural Science Foundation of China[2021004] ; DNL Fund[52106275] ; National Natural Science Foundation of China[2023-YBSF-442] ; Key R&D Program of Shaanxi Province
WOS关键词	SELF-SUSTAINED COMBUSTION ; NONTHERMAL PLASMA ; ATMOSPHERIC-PRESSURE ; SOLID-SOLUTIONS ; CE CATALYSTS ; REMOVAL ; DECOMPOSITION ; TEMPERATURE ; BENZENE ; OPTIMIZATION
WOS研究方向	Chemistry
语种	英语
WOS记录号	WOS:001144722400001
资助机构	National Natural Science Foundation of China ; DNL Fund ; National Natural Science Foundation of China ; Key R&D Program of Shaanxi Province
其他责任者	Ma, Yichen ; Bin, Feng
内容类型	期刊论文
源URL	[http://dspace.imech.ac.cn/handle/311007/94142]
专题	力学研究所_高温气体动力学国家重点实验室
推荐引用方式 GB/T 7714	Hu, Guangtao,Ma, Yichen,Hao, Qinglan,et al. Plasma-catalytic oxidation of toluene over MCeZrO_x/TiO₂ (M = Cu, Mn, Ni and Co) catalysts using a dielectric barrier discharge reactor[J]. NEW JOURNAL OF CHEMISTRY,2024,48(6):2624-2638.
APA	Hu, Guangtao,Ma, Yichen,Hao, Qinglan,Liu, Deliang,Dou, Baojuan,&宾峰.(2024).Plasma-catalytic oxidation of toluene over MCeZrO_x/TiO₂ (M = Cu, Mn, Ni and Co) catalysts using a dielectric barrier discharge reactor.NEW JOURNAL OF CHEMISTRY,48(6),2624-2638.
MLA	Hu, Guangtao,et al."Plasma-catalytic oxidation of toluene over MCeZrO_x/TiO₂ (M = Cu, Mn, Ni and Co) catalysts using a dielectric barrier discharge reactor".NEW JOURNAL OF CHEMISTRY 48.6(2024):2624-2638.