Optimizing the chlorine evolution reaction performance of Co(OH)2 catalyst for enhanced antifouling ability
Peng, Yating2,3,4; Wang, Peng2,3,4; Li, Jiawei2,3,4; Wu, Jiajia2,3,4; Lin, Feng1; Zhang, Dun2,3,4
刊名JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY
2023-02-25
卷号118页码:91-100
关键词Antifouling Chlorine evolution reaction Electrocatalysis Optical window
ISSN号1226-086X
DOI10.1016/j.jiec.2022.10.048
通讯作者Wang, Peng(wangpeng@qdio.ac.cn) ; Lin, Feng(linfeng@tio.org.cn)
英文摘要Underwater optical instruments are commonly plagued by biofouling. As one of the most useful antifoul -ing strategies, electrochemical chlorination is able to prevent biofouling efficiently, but the limited activ-ity and selectivity in chlorine evolution reaction (CER) restrict its practical applications. To address this problem, we focus on the optimization of CER performance of cobalt-based catalysts. In this work, we prepared Co(OH)2 with different forms, morphologies, and intercalations. By adopting linear sweep voltammetry and electrochemical active surface area analysis, it is demonstrated that the a-Co(OH)2 exhibits better CER performance than b-Co(OH)2 does, and the manipulation of a-Co(OH)2 morphology can help to further enhance CER performance. Meanwhile, the intercalation of a-Co(OH)2 plays a minor role in the CER. Furthermore, based on the screened synthetic condition, the optimized a-Co(OH)2 was applied for practical antifouling examination, and its excellent antifouling ability was verified by the investigation on bacteria attachment and glass transmittance. The findings in this work not only enrich our understanding on the effects of synthetic conditions on CER performance of cobalt-based catalysts, but also provide useful insights into the development of electrochemical antifouling strategies.(c) 2022 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.
资助项目Strategic Priority Research Pro-gram of Chinese Academy of Sciences ; National Natural Science Foundation of China ; Shandong Provincial Marine Science and Technology Projects ; [XDA23050104] ; [41922040]
WOS关键词COBALT HYDROXIDE ; OXYGEN EVOLUTION ; ALPHA-COBALT ; PHASE-TRANSFORMATION ; HIGHLY EFFICIENT ; ALPHA-CO(OH)(2) ; ELECTRODE ; ELECTROCATALYSIS ; SELECTIVITY ; NANOSHEETS
WOS研究方向Chemistry ; Engineering
语种英语
出版者ELSEVIER SCIENCE INC
WOS记录号WOS:000910594100001
内容类型期刊论文
源URL[http://ir.qdio.ac.cn/handle/337002/183293]  
专题海洋研究所_海洋腐蚀与防护研究发展中心
通讯作者Wang, Peng; Lin, Feng
作者单位1.Minist Nat Resources, Inst Oceanog 3, 184 Daxue Rd, Xiamen 361005, Peoples R China
2.Chinese Acad Sci, Inst Oceanol, Key Lab Marine Environm Corros & Biofouling, Qingdao 266071, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
4.Pilot Natl Lab Marine Sci & Technol Qingdao, Open Studio Marine Corros & Protect, 168 Wenhai Middle Rd, Qingdao 266237, Peoples R China
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Peng, Yating,Wang, Peng,Li, Jiawei,et al. Optimizing the chlorine evolution reaction performance of Co(OH)2 catalyst for enhanced antifouling ability[J]. JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY,2023,118:91-100.
APA Peng, Yating,Wang, Peng,Li, Jiawei,Wu, Jiajia,Lin, Feng,&Zhang, Dun.(2023).Optimizing the chlorine evolution reaction performance of Co(OH)2 catalyst for enhanced antifouling ability.JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY,118,91-100.
MLA Peng, Yating,et al."Optimizing the chlorine evolution reaction performance of Co(OH)2 catalyst for enhanced antifouling ability".JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY 118(2023):91-100.
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