Leaching of Sulfadiazine and Florfenicol in an Entisol of a Chicken-Raising Orchard: Impact of Manure-Derived Dissolved Organic Matter | |
Gbadegesin, Lanre Anthony2,3; Liu, Xinyu1,3; Tang, Xiangyu3; Liu, Chen3; Cui, Junfang3 | |
刊名 | AGRONOMY-BASEL |
2022-12-01 | |
卷号 | 12期号:12页码:17 |
关键词 | antibiotics leaching mass flux manure EEM-PARAFAC farmland |
ISSN号 | 2073-4395 |
DOI | 10.3390/agronomy12123228 |
英文摘要 | Antibiotic pollution from manured farmland soils is a major public concern, and their potential interaction with manure particles and/or manure-dissolved organic matter (DOM) often complicates their leaching behaviour. This study investigated the leaching of sulfadiazine (SDZ) and florfenicol (FFC) with manure-DOM in undisturbed field lysimeters and repacked soil columns under natural and simulated rainfall conditions. The results showed that manure-DOM reduced SDZ mass flux, but soil hydrological processes and heavy rainfall events led to accelerated leaching. FFC was more prone to leaching in a manured plot (0.48 mu g m(-2) h(-1)) compared to the control (0.12 mu g m(-2) h(-1)), suggesting DOM facilitated transport of FFC in the field lysimeter study via cotransport mechanisms favored by abundant macropores in the study site. In contrast, SDZ and FFC mobility were reduced in repacked soil columns under manure-DOM conditions, suggesting complexation and adsorption in matrix pores. Two kinetic site models and two-site nonequilibrium adsorption models revealed the existence of nonequilibrium conditions and kinetic sorption processes in the repacked column. FFC exhibited lower leaching potential compared to SDZ in both the repacked column and natural field conditions. Redundancy analyses revealed that FFC had a close relationship with humic-like components (C1 and C3), but SDZ was more related to the protein-like components (C2) of DOM. The presence of manure-DOM may decrease the ecological risks of highly mobile antibiotics under matrix flow through complexations and adsorption. However, a similar scenario in macroporous flow under heavy rainfalls may lead to accelerated leaching. |
资助项目 | National Natural Science Foundation of China ; Sichuan Science and Technology Program[41771521] ; [2022YFS0500] |
WOS关键词 | VETERINARY ANTIBIOTICS ; SULFONAMIDE ANTIBIOTICS ; FRACTURE FLOW ; SWINE MANURE ; TRANSPORT ; SOIL ; SURFACE ; FATE ; FLUORESCENCE ; GROUNDWATER |
WOS研究方向 | Agriculture ; Plant Sciences |
语种 | 英语 |
出版者 | MDPI |
WOS记录号 | WOS:000902107800001 |
资助机构 | National Natural Science Foundation of China ; Sichuan Science and Technology Program |
内容类型 | 期刊论文 |
源URL | [http://ir.imde.ac.cn/handle/131551/57051] |
专题 | 成都山地灾害与环境研究所_山地表生过程与生态调控重点实验室 |
通讯作者 | Liu, Chen; Cui, Junfang |
作者单位 | 1.Southwest Jiaotong Univ, Fac Geosci & Environm Engn, Chengdu 611756, Peoples R China 2.Univ Chinese Acad Sci, Int Coll, Beijing 100049, Peoples R China 3.Chinese Acad Sci, Inst Mt Hazards & Environm, Key Lab Mt Surface Proc & Ecol Regulat, Chengdu 610041, Peoples R China |
推荐引用方式 GB/T 7714 | Gbadegesin, Lanre Anthony,Liu, Xinyu,Tang, Xiangyu,et al. Leaching of Sulfadiazine and Florfenicol in an Entisol of a Chicken-Raising Orchard: Impact of Manure-Derived Dissolved Organic Matter[J]. AGRONOMY-BASEL,2022,12(12):17. |
APA | Gbadegesin, Lanre Anthony,Liu, Xinyu,Tang, Xiangyu,Liu, Chen,&Cui, Junfang.(2022).Leaching of Sulfadiazine and Florfenicol in an Entisol of a Chicken-Raising Orchard: Impact of Manure-Derived Dissolved Organic Matter.AGRONOMY-BASEL,12(12),17. |
MLA | Gbadegesin, Lanre Anthony,et al."Leaching of Sulfadiazine and Florfenicol in an Entisol of a Chicken-Raising Orchard: Impact of Manure-Derived Dissolved Organic Matter".AGRONOMY-BASEL 12.12(2022):17. |
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