Glass-like Cuprous Iodide Complexes with Photoluminescence Tuning and Two-photon Emission Properties
Yin, Shaoyun2,3; Zhang, Luyin1,3; Wang, Zheng3; Pan, Mei3
刊名Gaodeng Xuexiao Huaxue Xuebao/Chemical Journal of Chinese Universities
2020-04-10
卷号41期号:4页码:646-651
关键词Charge transfer Copper compounds Diffraction Glass Ligands Photons Single crystals X ray powder diffraction X rays Biological imaging Different solvents Fluorescence band Luminescent colors Photon emissions Photophysical properties Two-photon emission X-ray single-crystal diffraction
ISSN号02510790
DOI10.7503/cjcu20190657
英文摘要Eight kinds of glass-like cuprous iodide complexes with Cu2I2L2 configurations were self-assembled from CuI with semi-flexible 3-pebtd ligand with unsaturated π-backbone and bipodal pyridine terminals in different solvents. The complexes were characterized by X-ray single crystal diffraction, X-ray powder diffraction, elemental analysis, and so on. The photophysical properties of the complexes were studied, and the results show that the one-photon emissions of the complexes obtained in different solvents show single fluorescence bands assigning to the halogen to ligand charge transfer(3XLCT). The luminescent colors of the complexes were adjustable from 492 to 518 nm, and the quantum yield was 33.1%~68.5%. At the same time, these complexes exhibit excellent two-photon emission properties and are expected to be used in the field of biological imaging. © 2020, Higher Education Press. All right reserved.
WOS研究方向Chemistry
语种中文
出版者Higher Education Press Limited Company
WOS记录号WOS:000539094500007
内容类型期刊论文
源URL[http://ir.lut.edu.cn/handle/2XXMBERH/151069]  
专题省部共建有色金属先进加工与再利用国家重点实验室
作者单位1.State Key Laboratory of Advanced Processing and Recycling of Nonferrous Metals, School of Materials Science and Engineering, Lanzhou University of Technology, Lanzhou; 730050, China
2.Analysis and Test Center, Guangdong University of Technology, Guangzhou; 510006, China;
3.School of Chemistry, Sun Yat-Sen University, Guangzhou; 510275, China;
推荐引用方式
GB/T 7714
Yin, Shaoyun,Zhang, Luyin,Wang, Zheng,et al. Glass-like Cuprous Iodide Complexes with Photoluminescence Tuning and Two-photon Emission Properties[J]. Gaodeng Xuexiao Huaxue Xuebao/Chemical Journal of Chinese Universities,2020,41(4):646-651.
APA Yin, Shaoyun,Zhang, Luyin,Wang, Zheng,&Pan, Mei.(2020).Glass-like Cuprous Iodide Complexes with Photoluminescence Tuning and Two-photon Emission Properties.Gaodeng Xuexiao Huaxue Xuebao/Chemical Journal of Chinese Universities,41(4),646-651.
MLA Yin, Shaoyun,et al."Glass-like Cuprous Iodide Complexes with Photoluminescence Tuning and Two-photon Emission Properties".Gaodeng Xuexiao Huaxue Xuebao/Chemical Journal of Chinese Universities 41.4(2020):646-651.
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