In situ synthesis of Fe2O3 nanosphere/Co3O4 nanowire-connected reduced graphene oxide hybrid networks for high-performance supercapacitors
Wang, Yan2,3; Zhou, Jianhao2; Zhou, Zhiyu2; Lv, Huifang2; Gu, Bingni1,4,5; Wang, Kuangye1,4,5; Chen, Zexiang2,3; Yan, Xinyu2; Zhang, Jijun2; Liu, Wen-Wu6
刊名NANOSCALE
2021-09-28
卷号13期号:36页码:15431-15444
ISSN号2040-3364
DOI10.1039/d1nr00126d
英文摘要Three-dimensional (3D) hybrid networks consisting of reduced graphene oxide (rGO) sheets interconnected by Co3O4 nanowires (rGO/Co3O4), followed by the decoration of Fe2O3 nanospheres (NSs) (rGO/Co3O4@Fe2O3), were demonstrated by a facile hydrothermal method, with which the rGO/Co3O4 networks acted as nucleation sites for the in situ synthesis of Fe2O3 NSs. The intimate contacts between rGO, Co3O4 NWs and Fe2O3 NSs, which result in an excellent conductive behavior, provide a unique structure with huge potential for electrochemical property promoted electrochemical supercapacitors. The rGO/Co3O4@Fe2O3 hybrid networks as electrodes exhibit a high capacitance of 784 F g(-1) at 1 A g(-1) with 83% retention of the initial capacitance as the current density increases from 1 to 10 A g(-1), which is explained by the graphene-based interconnected structure owing to the advantages of accommodating the volume expansion between Co3O4 NWs and Fe2O3 NSs. The supercapacitor was assembled by applying a nickel aluminum layered double hydroxide (NiAl-LDH) structure and rGO/Co3O4@Fe2O3 as the electrode materials and yields an energy density of 70.78 W h kg(-1) at a power density of 0.29 kW kg(-1). The energy density can maintain 24.24 W h kg(-1) with 9.94 kW kg(-1).
WOS研究方向Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics
语种英语
出版者ROYAL SOC CHEMISTRY
WOS记录号WOS:000694664800001
内容类型期刊论文
源URL[http://ir.lut.edu.cn/handle/2XXMBERH/148523]  
专题省部共建有色金属先进加工与再利用国家重点实验室
作者单位1.Natl Tsing Hua Univ, Frontier Res Ctr Fundamental & Appl Sci Matters, Hsinchu 30013, Taiwan;
2.Univ Elect Sci & Technol China, Sch Optoelect Sci & Engn UESTC, Jianshe North Rd 4, Chengdu 610054, Peoples R China;
3.Sichuan Prov Key Lab Display Sci & Technol, Jianshe North Rd 4, Chengdu 610054, Peoples R China;
4.Natl Tsing Hua Univ, Dept Mat Sci & Engn, Hsinchu 30013, Taiwan;
5.Natl Sun Yat Sen Univ, Dept Phys, Kaohsiung 80424, Taiwan;
6.Lanzhou Univ Technol, State Key Lab Adv Proc & Recycling Nonferrous Met, Lanzhou 730050, Peoples R China
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Wang, Yan,Zhou, Jianhao,Zhou, Zhiyu,et al. In situ synthesis of Fe2O3 nanosphere/Co3O4 nanowire-connected reduced graphene oxide hybrid networks for high-performance supercapacitors[J]. NANOSCALE,2021,13(36):15431-15444.
APA Wang, Yan.,Zhou, Jianhao.,Zhou, Zhiyu.,Lv, Huifang.,Gu, Bingni.,...&Chueh, Yu-Lun.(2021).In situ synthesis of Fe2O3 nanosphere/Co3O4 nanowire-connected reduced graphene oxide hybrid networks for high-performance supercapacitors.NANOSCALE,13(36),15431-15444.
MLA Wang, Yan,et al."In situ synthesis of Fe2O3 nanosphere/Co3O4 nanowire-connected reduced graphene oxide hybrid networks for high-performance supercapacitors".NANOSCALE 13.36(2021):15431-15444.
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