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In-situ fabrication of a phase continuous transition Bismuth iodide/Bismuth niobate heterojunction: Interface regulation and the enhanced photodegradation mechanism
Zhang, Huining1,2,3; Xiao, Yankui1; Tian, Lihong1; Tang, Yuling1; Liu, Xingmao1; Shi, Zhongyu1; Wu, Zhiguo2; Wei, Zhiqiang1
刊名CHEMICAL PHYSICS
2022-10-01
卷号562
关键词Bismuthiodide Bismuthniobate Interfacestructure RhB Photocatalysis
ISSN号0301-0104
DOI10.1016/j.chemphys.2022.111644
英文摘要A direct Z-scheme bismuth iodide/bismuth niobate (BiOI/BiNbO) heterojunction photocatalysts with a different molar ratio of Bi/Nb were prepared. The structural and photoelectrical properties of these as-prepared samples were investigated, photocatalytic activity and different effect factors were evaluated. The experiment results indicated that the highest RhB degradation efficiency was that of the sample with Bi/Nb = 0.7, bringing a lower interface resistance that facilitate the separation and transportation of photogenerated carrier. Furthermore, active species trapping experiments suggested that center dot OH was the most contributor responsible for the RhB photocatalytic process. The photodegradation mechanism and a reasonable degradation pathway were further proposed by DFT theoretical calculation.
WOS研究方向Chemistry ; Physics
语种英语
出版者ELSEVIER
WOS记录号WOS:000830884000001
内容类型期刊论文
源URL[http://ir.lut.edu.cn/handle/2XXMBERH/159442]  
专题土木工程学院
理学院
作者单位1.Lanzhou Univ Technol, Sch Civil Engn, Lanzhou 730050, Peoples R China;
2.Gansu Acad Sci, Inst Nanomat Applicat Technol, Lanzhou 730030, Peoples R China;
3.Lanzhou Univ Technol, Sch Civil Engn, Langongping Rd 287, Lanzhou 730050, Peoples R China
推荐引用方式
GB/T 7714
Zhang, Huining,Xiao, Yankui,Tian, Lihong,et al. In-situ fabrication of a phase continuous transition Bismuth iodide/Bismuth niobate heterojunction: Interface regulation and the enhanced photodegradation mechanism[J]. CHEMICAL PHYSICS,2022,562.
APA Zhang, Huining.,Xiao, Yankui.,Tian, Lihong.,Tang, Yuling.,Liu, Xingmao.,...&Wei, Zhiqiang.(2022).In-situ fabrication of a phase continuous transition Bismuth iodide/Bismuth niobate heterojunction: Interface regulation and the enhanced photodegradation mechanism.CHEMICAL PHYSICS,562.
MLA Zhang, Huining,et al."In-situ fabrication of a phase continuous transition Bismuth iodide/Bismuth niobate heterojunction: Interface regulation and the enhanced photodegradation mechanism".CHEMICAL PHYSICS 562(2022).
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