Effects of LiCl template amount on structure, morphology, and electrochemical performance of porous Si@C anodes | |
Dong, Hong1,2; Ding, Hao2; Zhang, Ningshuang1,2,3; Wang, Jie2; Linhu3; Song2; Wang, Peng2; Song, Ru2; Sun, Yongkun2; Li, Shiyou1,2,3 | |
刊名 | Ionics |
2022-06-01 | |
卷号 | 28期号:6页码:2635-2648 |
关键词 | Additives Anodes Carbon Chlorine compounds Density functional theory Lithium compounds Pore size Porous silicon Silicon compounds Size distribution Carbon anodes Density-functional theory calculations Electrochemical performance Pore-size distribution Porous silicon carbon Property Silicon carbon Silicon-based Structure performance Volume change |
ISSN号 | 0947-7047 |
DOI | 10.1007/s11581-022-04526-2 |
英文摘要 | Porous silicon carbon (Si@C) has been regarded as a promising candidate to overcome volume change of silicon-based anodes. However, the relationship between pore size distribution and properties of porous Si@C materials is not clear. Herein, porous materials with different pore size structures are synthesized by adjusting the proportion of LiCl additives in the template, which is used to study the effect of pore size distribution on the properties of batteries. The results show that the porous Si@C prepared with the content of 10% LiCl templates has the perfect electrochemical comprehensive performance. In addition, we have utilized the density functional theory (DFT) calculation methods to further study the effect of carbon defects on the material properties. Graphical abstract: [Figure not available: see fulltext.]. © 2022, The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature. |
语种 | 英语 |
出版者 | Springer Science and Business Media Deutschland GmbH |
内容类型 | 期刊论文 |
源URL | [http://ir.lut.edu.cn/handle/2XXMBERH/158498] |
专题 | 石油化工学院 |
作者单位 | 1.Key Laboratory of Low Carbon Energy and Chemical Engineering of Gansu Province, Lanzhou; 730050, China; 2.School of Petrochemical Technology, Lanzhou University of Technology, 36 Pengjiaping Road, Gansu Province, Lanzhou; 730050, China; 3.Gansu Engineer in Laboratory of Cathode Material for Lithium-Ion Battery, Baiyin; 730900, China |
推荐引用方式 GB/T 7714 | Dong, Hong,Ding, Hao,Zhang, Ningshuang,et al. Effects of LiCl template amount on structure, morphology, and electrochemical performance of porous Si@C anodes[J]. Ionics,2022,28(6):2635-2648. |
APA | Dong, Hong.,Ding, Hao.,Zhang, Ningshuang.,Wang, Jie.,Linhu.,...&Li, Shiyou.(2022).Effects of LiCl template amount on structure, morphology, and electrochemical performance of porous Si@C anodes.Ionics,28(6),2635-2648. |
MLA | Dong, Hong,et al."Effects of LiCl template amount on structure, morphology, and electrochemical performance of porous Si@C anodes".Ionics 28.6(2022):2635-2648. |
个性服务 |
查看访问统计 |
相关权益政策 |
暂无数据 |
收藏/分享 |
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。
修改评论