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Hazardous characteristics and transformation mechanism in hydrometallurgical disposing strategy of secondary aluminum dross
Li, Yong1,2; Qin, Ziyi1,3; Li, Chunlei1; Qu, Yi4; Wang, Haibin1; Peng, Li1; Wang, Yi1
刊名JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
2021-12
卷号9期号:6
关键词Secondary aluminum dross Harmlessness Hydrometallurgy Kinetics Sustainable
DOI10.1016/j.jece.2021.106470
英文摘要To further understand the transformation behavior of active phase during hydrometallurgical disposal, and then provide theoretical guidance for the recovery and utilization of secondary aluminum dross (SAD) valuable resource, factors affecting the harmlessness efficiency, transformation behavior of active phase and kinetics of the leaching process investigated. The results indicate that harmless residues can be achieved when treated at the conditions of liquid-solid ratio of 5, leaching temperature of 80 degrees C, extracting time of 4 h and SAD particle size less than 2000 mu m. The capacity of emissing gas, which is composed of small amount of ammonia, methane and dominant proportion of hydrogen, increases with the enlargement of particle size. The small particles with relative high proportion of aluminum carbide and aluminum nitride tend to release more methane and ammonia. During hydrometallurgical process, the active substances generate intermediate phase of aluminum hydroxide spontaneously, cover on the interface of SAD particles, and then react with acidic or alkaline medium. The hydrolysis of active phases and the dissolution of fluoride follow the Avrami-Erofeyev Model and internal diffusion model, respectively, while the rate both of them are all controlled by diffusion. This work is hopeful for providing a deep insight into disposal and comprehensive utilization of SAD.
WOS研究方向Engineering
语种英语
出版者ELSEVIER SCI LTD
WOS记录号WOS:000707256200002
内容类型期刊论文
源URL[http://ir.lut.edu.cn/handle/2XXMBERH/150111]  
专题石油化工学院
作者单位1.Lanzhou Univ Technol, Coll Petrochem Technol, 36 Pengjiaping Rd, Lanzhou 730050, Gansu, Peoples R China;
2.Zhongnan Testing Technol Co Ltd, Wuhan 430051, Peoples R China;
3.Wuchang Polytech Coll, Wuhan 430202, Peoples R China;
4.Aluminum Corp China Ltd, Lanzhou Branch, Lanzhou 730050, Peoples R China
推荐引用方式
GB/T 7714
Li, Yong,Qin, Ziyi,Li, Chunlei,et al. Hazardous characteristics and transformation mechanism in hydrometallurgical disposing strategy of secondary aluminum dross[J]. JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING,2021,9(6).
APA Li, Yong.,Qin, Ziyi.,Li, Chunlei.,Qu, Yi.,Wang, Haibin.,...&Wang, Yi.(2021).Hazardous characteristics and transformation mechanism in hydrometallurgical disposing strategy of secondary aluminum dross.JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING,9(6).
MLA Li, Yong,et al."Hazardous characteristics and transformation mechanism in hydrometallurgical disposing strategy of secondary aluminum dross".JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING 9.6(2021).
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