Methanol to Aromatic Reaction over HZSM-5: Co-Effect Desilication and SiO2 Deposition | |
Li, Hui; Dong, Peng; Ji, Dong; Zhao, Xinhong; Li, Chunqiang; Li, Guixian | |
刊名 | KINETICS AND CATALYSIS |
2021-05 | |
卷号 | 62期号:3页码:418-427 |
关键词 | HZSM-5 methanol p-xylene selectivity MTA reaction |
ISSN号 | 0023-1584 |
DOI | 10.1134/S0023158421030058 |
英文摘要 | Inthis work Si/HZSM-5-0.09M catalyst was prepared using desilication and regrowth of SiO2 method, which was characterized by XRF, XRD, SEM, NH3-TPD, and N-2 adsorption/desorption. Meanwhile, the structure-activity relationship was comprehensively discussed. The results revealed that the aromatics total selectivity of Si/HZSM-5-0.09M catalyst was significantly improved, from 33 to 54.8% compared to HZSM-5 under the optimal conditions. Also, the selectivity of p-xylene over Si/HZSM-5-0.09M catalyst increased from 4.6 to 19.8% compared to HZSM-5. The total selectivity of benzene, toluene, and xylene over Si/HZSM-5-0.09M catalyst was significantly improved by 66.1% compared to that of HZSM-5. Thus, an excellent catalytic effect has been found, which indicates that the SiO2 deposition on the surface favors the enhancement of the p-xylene selectivity in the methanol aromatization reaction. [GRAPHICS] . |
WOS研究方向 | Chemistry |
语种 | 英语 |
出版者 | PLEIADES PUBLISHING INC |
WOS记录号 | WOS:000660025600010 |
内容类型 | 期刊论文 |
源URL | [http://ir.lut.edu.cn/handle/2XXMBERH/148679] |
专题 | 石油化工学院 |
作者单位 | Lanzhou Univ Technol, Coll Petrochem Technol, Lanzhou 730050, Peoples R China |
推荐引用方式 GB/T 7714 | Li, Hui,Dong, Peng,Ji, Dong,et al. Methanol to Aromatic Reaction over HZSM-5: Co-Effect Desilication and SiO2 Deposition[J]. KINETICS AND CATALYSIS,2021,62(3):418-427. |
APA | Li, Hui,Dong, Peng,Ji, Dong,Zhao, Xinhong,Li, Chunqiang,&Li, Guixian.(2021).Methanol to Aromatic Reaction over HZSM-5: Co-Effect Desilication and SiO2 Deposition.KINETICS AND CATALYSIS,62(3),418-427. |
MLA | Li, Hui,et al."Methanol to Aromatic Reaction over HZSM-5: Co-Effect Desilication and SiO2 Deposition".KINETICS AND CATALYSIS 62.3(2021):418-427. |
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