A Novel Fluorescent Probe Based on Pyrazole-Pyrazoline for Fe (III) Ions Recognition | |
Zhang, Ying-Peng1; Li, Xiang-Fang1; Yang, Yun-Shang1; Wang, Jing-Li2; Zhao, Yu-Chen1; Xue, Ji-Jun2 | |
刊名 | Journal of Fluorescence
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2021 | |
卷号 | 31期号:1页码:29-38 |
关键词 | Binding energy Fluorescence Fluorescence spectroscopy Metal ions Metals Probes Uranium metallography Vanadium metallography Fluorescence intensities Fluorescent probes Selective recognition Selectivity and sensitivity Sensing mechanism Tetra-hydrofuran Theoretical calculations UV absorption spectrum |
ISSN号 | 10530509 |
DOI | 10.1007/s10895-020-02632-w |
英文摘要 | Firstly, a novel pyrazole-pyrazoline fluorescent probe was developed and synthesized. The probe can be used to determine Fe3+ ions in a series of cations in tetrahydrofuran aqueous solution with high selectivity and high sensitivity. After the addition of iron ions, the fluorescence intensity is significantly reduced, Its structure was characterized by 1H NMR, 13C NMR and HR-ESI-MS. UV absorption spectra and Fluorescence spectroscopy were used to study the selective recognition of probe M on metal ions. The probe M can selectivity and sensitivity to distinguish the target ion from other ions through different fluorescence phenomena. In addition, the binding modes of M with Fe3+ were proved to be 1:1 stoichiometry in the complexes by Job’s plot, IR results. The combination of probe M and iron ions is 1:1, and the detection limit is 3.9 × 10−10 M. The binding mode and sensing mechanism of M with Fe3+ was verified by theoretical calculations using Gaussian 09 based on B3LYP/6-31G(d) basis. © 2020, Springer Science+Business Media, LLC, part of Springer Nature. |
WOS研究方向 | Biochemistry & Molecular Biology ; Chemistry |
语种 | 英语 |
出版者 | Springer |
WOS记录号 | WOS:000577489500001 |
内容类型 | 期刊论文 |
源URL | [http://ir.lut.edu.cn/handle/2XXMBERH/147228] ![]() |
专题 | 石油化工学院 |
作者单位 | 1.School of Petrochemical Engineering, Lanzhou University of Technology, Lanzhou; 730050, China; 2.College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou; 730000, China |
推荐引用方式 GB/T 7714 | Zhang, Ying-Peng,Li, Xiang-Fang,Yang, Yun-Shang,et al. A Novel Fluorescent Probe Based on Pyrazole-Pyrazoline for Fe (III) Ions Recognition[J]. Journal of Fluorescence,2021,31(1):29-38. |
APA | Zhang, Ying-Peng,Li, Xiang-Fang,Yang, Yun-Shang,Wang, Jing-Li,Zhao, Yu-Chen,&Xue, Ji-Jun.(2021).A Novel Fluorescent Probe Based on Pyrazole-Pyrazoline for Fe (III) Ions Recognition.Journal of Fluorescence,31(1),29-38. |
MLA | Zhang, Ying-Peng,et al."A Novel Fluorescent Probe Based on Pyrazole-Pyrazoline for Fe (III) Ions Recognition".Journal of Fluorescence 31.1(2021):29-38. |
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