High-Performance and Ultra-Stable Aqueous Supercapacitors Based on a Green and Low-Cost Water-In-Salt Electrolyte | |
Guo, Junhong3; Ma, Yalan3,5; Zhao, Kun2; Wang, Yue1,5; Yang, Baoping3; Cui, Jinfeng3; Yan, Xingbin4,5 | |
刊名 | ChemElectroChem |
2019-10-31 | |
卷号 | 6期号:21页码:5433-5438 |
关键词 | Capacitance Carbon Costs Electrolytes Nitrates Sodium nitrate Supercapacitor Viscosity Capacitance retention Electrochemical stabilities Electrolyte systems High conductivity High specific capacitances Low costs Rate capabilities Salt electrolytes |
ISSN号 | 2196-0216 |
DOI | 10.1002/celc.201901591 |
英文摘要 | The emergence of "water-in-salt" carbon-based supercapacitors presents great potential for further improving the energy density, owing to the extended electrochemical stability window. However, not only low conductivity and high viscosity hinder the superior rate performance, but also the high cost of salts limits their commercialization. Here, we report a low-cost concentrated sodium nitrate electrolyte for high-performance and ultra-stable supercapacitors, based on good electrochemical stability, high conductivity, and low viscosity. In the wide operation voltage range of 0–2.1 V, the constructed symmetric supercapacitor based on commercial active carbon exhibits a high specific capacitance of 32.68 F g−1 at 1 A g−1. Moreover, superior rate capability (83 % capacitance retention from 1 to 20 A g−1) and excellent cycle stability (90 % capacitance retention after 9000 cycles) are also demonstrated. Consequently, this electrolyte system could be the most attractive candidate for promising carbon-based supercapacitors to further improve the energy density. © 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim |
WOS研究方向 | Electrochemistry |
语种 | 英语 |
出版者 | Wiley-VCH Verlag |
WOS记录号 | WOS:000496539000011 |
内容类型 | 期刊论文 |
源URL | [http://ir.lut.edu.cn/handle/2XXMBERH/114810] |
专题 | 石油化工学院 图书馆 实验室建设与管理处 |
作者单位 | 1.School of Physical Science and Technology Lanzhou University, Lanzhou; 730050, China; 2.State Key Laboratory of Advanced Processing and Recycling of Nonferrous Metals School of Materials Science and Engineering, Lanzhou University of Technology, Lanzhou; 730050, China; 3.Department of Chemical Engineering and Technology Institution School of Petrochemical Engineering, Lanzhou University of Technology, Lanzhou; 730050, China; 4.Dalian National Laboratory for Clean Energy Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian; 116000, China 5.Laboratory of Clean Energy Chemistry and Materials, State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou; 730050, China; |
推荐引用方式 GB/T 7714 | Guo, Junhong,Ma, Yalan,Zhao, Kun,et al. High-Performance and Ultra-Stable Aqueous Supercapacitors Based on a Green and Low-Cost Water-In-Salt Electrolyte[J]. ChemElectroChem,2019,6(21):5433-5438. |
APA | Guo, Junhong.,Ma, Yalan.,Zhao, Kun.,Wang, Yue.,Yang, Baoping.,...&Yan, Xingbin.(2019).High-Performance and Ultra-Stable Aqueous Supercapacitors Based on a Green and Low-Cost Water-In-Salt Electrolyte.ChemElectroChem,6(21),5433-5438. |
MLA | Guo, Junhong,et al."High-Performance and Ultra-Stable Aqueous Supercapacitors Based on a Green and Low-Cost Water-In-Salt Electrolyte".ChemElectroChem 6.21(2019):5433-5438. |
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